Int. J. Mol. Sci. 2013, 14(9), 18200-18214; doi:10.3390/ijms140918200

Synthesis and Characterizations of Melamine-Based Epoxy Resins

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Received: 8 July 2013; in revised form: 2 August 2013 / Accepted: 20 August 2013 / Published: 5 September 2013
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: A new, easy and cost-effective synthetic procedure for the preparation of thermosetting melamine-based epoxy resins is reported. By this innovative synthetic method, different kinds of resins can be obtained just by mixing the reagents in the presence of a catalyst without solvent and with mild curing conditions. Two types of resins were synthesized using melamine and a glycidyl derivative (resins I) or by adding a silane derivative (resin II). The resins were characterized by means of chemical-physical and thermal techniques. Experimental results show that all the prepared resins have a good thermal stability, but differ for their mechanical properties: resin I exhibits remarkable stiffness with a storage modulus value up to 830 MPa at room temperature, while lower storage moduli were found for resin II, indicating that the presence of silane groups could enhance the flexibility of these materials. The resins show a pot life higher than 30 min, which makes these resins good candidates for practical applications. The functionalization with silane terminations can be exploited in the formulation of hybrid organic-inorganic composite materials.
Keywords: epoxy resin; melamine; glycidyl derivative; IR; DSC; DMA; glass transition; crosslinking reaction; synthesis
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MDPI and ACS Style

Ricciotti, L.; Roviello, G.; Tarallo, O.; Borbone, F.; Ferone, C.; Colangelo, F.; Catauro, M.; Cioffi, R. Synthesis and Characterizations of Melamine-Based Epoxy Resins. Int. J. Mol. Sci. 2013, 14, 18200-18214.

AMA Style

Ricciotti L, Roviello G, Tarallo O, Borbone F, Ferone C, Colangelo F, Catauro M, Cioffi R. Synthesis and Characterizations of Melamine-Based Epoxy Resins. International Journal of Molecular Sciences. 2013; 14(9):18200-18214.

Chicago/Turabian Style

Ricciotti, Laura; Roviello, Giuseppina; Tarallo, Oreste; Borbone, Fabio; Ferone, Claudio; Colangelo, Francesco; Catauro, Michelina; Cioffi, Raffaele. 2013. "Synthesis and Characterizations of Melamine-Based Epoxy Resins." Int. J. Mol. Sci. 14, no. 9: 18200-18214.

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