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Int. J. Mol. Sci. 2000, 1(3), 49-60; doi:10.3390/ijms1030049
Article

The Magnetic Shielding Polarizabilities of Some Tetrahedral Molecules

*  and
Received: 25 May 2000; Accepted: 23 August 2000 / Published: 9 September 2000
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Abstract: TMS is the commonest standard reference for both protons and 13C NMR spectroscopy. The Magnetic Shielding and its Polarizabilities, plus the static polarizability have been calculated for TMS, tetramethyl ammonium cation and 2,2-dimethylpropane. An investigation of continuum solvation effects on these highly symmetrical molecules, whose first surviving electric moment is the octopole, showed interaction with solvent makes little change to these magnetic properties. This small change is however consistent with both the high symmetry of the molecules and the available extensive experimental data for TMS. A rationalization of the signs and magnitudes of A in a sequence of related molecules has been suggested.
Keywords: Magnetic; Shielding; Buckingham and TDMS Magnetic; Shielding; Buckingham and TDMS
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Grayson, M.; Chittenden, P. The Magnetic Shielding Polarizabilities of Some Tetrahedral Molecules. Int. J. Mol. Sci. 2000, 1, 49-60.

AMA Style

Grayson M, Chittenden P. The Magnetic Shielding Polarizabilities of Some Tetrahedral Molecules. International Journal of Molecular Sciences. 2000; 1(3):49-60.

Chicago/Turabian Style

Grayson, Martin; Chittenden, Paul. 2000. "The Magnetic Shielding Polarizabilities of Some Tetrahedral Molecules." Int. J. Mol. Sci. 1, no. 3: 49-60.


Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert