Molecules 2004, 9(11), 949-956; doi:10.3390/91100949
Article

Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione)

1, 1,* email, 1 and 2,* email
Received: 10 March 2004; Accepted: 30 August 2004 / Published: 30 November 2004
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Two mononuclear complexes, [Ni(acac)2]·0.5CH3OH (1) and[Co(acac)2NO3]·2H2O (2) (acac = pentane-2,4-dione), have been synthesized andcharacterized by single crystal X-ray analysis. Complex 1 crystallizes in the monoclinicspace group P21/c with a = 9.295(4), b = 11.450(5), c = 12.974(6) å, V = 1379.1(11) å3,β = 92.854(7), and Z = 4. Complex 2 crystallizes in the triclinic space group P(-1) with a= 8.153(9), b = 9.925(11), c = 10.355(12), V = 746.3(15) å3, α = 70.530(16), β =71.154(15), γ = 80.698(16) and Z = 2. Complex 1 has a one-dimensional chain-likestructure, which is extended by weak hydrogen contacts, while complex 2 shows a three–dimensional network structure.
Keywords: Pentane-2; 4-dione; crystal structure; cobalt(III) complex; nickel(II) complex
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MDPI and ACS Style

Qu, Y.; Zhu, H.-L.; You, Z.-L.; Tan, M.-Y. Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione). Molecules 2004, 9, 949-956.

AMA Style

Qu Y, Zhu H-L, You Z-L, Tan M-Y. Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione). Molecules. 2004; 9(11):949-956.

Chicago/Turabian Style

Qu, Yang; Zhu, Hai-Liang; You, Zhong-Lu; Tan, Min-Yu. 2004. "Synthesis and Characterization of the Complexes of Pentane-2,4-dione with Nickel(II) and Cobalt(III): [Ni(acac)2]·0.5CH3OH and [Co(acac)2NO3]·2H2O (acac = Pentane-2,4-dione)." Molecules 9, no. 11: 949-956.

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