Next Article in Journal
Constituents from Moghat, the Roots of Glossostemon bruguieri (Desf.)
Previous Article in Journal
Peter Karuso and Paul J. Scheuer, Natural Products from Three Nudibranchs: Nembrotha kubaryana, Hypselodoris infucata and Chromodoris petechialis, Molecules, 2002, 7, 1-6
Molecules 2003, 8(8), 608-613; doi:10.3390/80800608
Article

A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation

* , ,  and
Received: 7 April 2003 / Revised: 7 July 2003 / Accepted: 20 July 2003 / Published: 31 July 2003
Download PDF [62 KB, uploaded 18 June 2014]

Abstract

An improved method for the generation of dichlorocarbene was developed that utilizes ultrasound in the reaction of carbon tetrachloride with magnesium. High yields of gem-dichlorocyclopropane derivatives can be obtained in the presence of olefins by this method.
Keywords: Dichlorocarbene; gem-dichlorocyclopropanes; ultrasonic irradiation; olefin addition; magnesium Dichlorocarbene; gem-dichlorocyclopropanes; ultrasonic irradiation; olefin addition; magnesium
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote
MDPI and ACS Style

Lin, H.; Yang, M.; Huang, P.; Cao, W. A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation. Molecules 2003, 8, 608-613.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here

Comments

Cited By

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert