Next Article in Journal
Constituents from Moghat, the Roots of Glossostemon bruguieri (Desf.)
Previous Article in Journal
Peter Karuso and Paul J. Scheuer, Natural Products from Three Nudibranchs: Nembrotha kubaryana, Hypselodoris infucata and Chromodoris petechialis, Molecules, 2002, 7, 1-6
Molecules 2003, 8(8), 608-613; doi:10.3390/80800608
Article

A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation

* , ,  and
Department of Chemistry, Shanghai University, Shanghai, 200436, P.R. China
* Author to whom correspondence should be addressed.
Received: 7 April 2003 / Revised: 7 July 2003 / Accepted: 20 July 2003 / Published: 31 July 2003
View Full-Text   |   Download PDF [62 KB, uploaded 18 June 2014]   |  

Abstract

An improved method for the generation of dichlorocarbene was developed that utilizes ultrasound in the reaction of carbon tetrachloride with magnesium. High yields of gem-dichlorocyclopropane derivatives can be obtained in the presence of olefins by this method.
Keywords: Dichlorocarbene; gem-dichlorocyclopropanes; ultrasonic irradiation; olefin addition; magnesium Dichlorocarbene; gem-dichlorocyclopropanes; ultrasonic irradiation; olefin addition; magnesium
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
SciFeed

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote |
RIS
MDPI and ACS Style

Lin, H.; Yang, M.; Huang, P.; Cao, W. A Facile Procedure for the Generation of Dichlorocarbene from the Reaction of Carbon Tetrachloride and Magnesium using Ultrasonic Irradiation. Molecules 2003, 8, 608-613.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here

Comments

[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert