Molecules 2003, 8(11), 780-787; doi:10.3390/81100780

Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate

1, 1, 1, 1,* email, 2 and 3
Published: 15 November 2003
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The tridentate ligand N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane (L) has been prepared in one step by condensation of two equivalents of 1-hydroxymethyl-3,5-dimethylpyrazole with one equivalent of 2-aminoethanol. This reaction is carried out under microwave irradiation (60 W) in the absence of solvent for 20 min [1]. Using this ligand L a new Cu(II) dinitrate complex has been prepared. The singlecrystal X-ray structure of the title compound, [N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane] (3,5-dimethylpyrazole)copper(II) dinitrate, revels that the copper (II) ion is coordinated to two pyrazole nitrogens, one tertiary amine nitrogen of the ligand L and 3,5-dimethylpyrazole, and in the apical position by an alcohol O atom.
Keywords: Structure; copper complex; tripod; pyrazole; tridentate ligand
PDF Full-text Download PDF Full-Text [57 KB, uploaded 18 June 2014 19:26 CEST]

Export to BibTeX |

MDPI and ACS Style

El Kodadi, M.; Malek, F.; Touzani, R.; Ramdani, A.; El Kadiri, S.; Eddike, D. Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate. Molecules 2003, 8, 780-787.

AMA Style

El Kodadi M, Malek F, Touzani R, Ramdani A, El Kadiri S, Eddike D. Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate. Molecules. 2003; 8(11):780-787.

Chicago/Turabian Style

El Kodadi, Mohamed; Malek, Fouad; Touzani, Rachid; Ramdani, Abdelkrim; El Kadiri, Sghir; Eddike, Driss. 2003. "Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate." Molecules 8, no. 11: 780-787.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert