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Molecules 2003, 8(11), 780-787; doi:10.3390/81100780
Article

Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate

1, 1, 1, 1,* , 2 and 3
1 Laboratory of Physical Organic Chemistry, Department of Chemistry, Faculty of Sciences, University Mohammed The First, BP 524, 60 000 Oujda, Morocco 2 Laboratory of Chemistry of the Environment and Materials, Department of Chemistry, Faculty of Sciences, University Mohammed The First, BP 524, 60 000 Oujda, Morocco 3 Laboratory of Inorganic Solid Chemistry, Department of Chemistry, Faculty of Sciences, University Mohammed The First, BP 524, 60 000 Oujda, Morocco
* Author to whom correspondence should be addressed.
Published: 15 November 2003
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Abstract

The tridentate ligand N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane (L) has been prepared in one step by condensation of two equivalents of 1-hydroxymethyl-3,5-dimethylpyrazole with one equivalent of 2-aminoethanol. This reaction is carried out under microwave irradiation (60 W) in the absence of solvent for 20 min [1]. Using this ligand L a new Cu(II) dinitrate complex has been prepared. The singlecrystal X-ray structure of the title compound, [N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane] (3,5-dimethylpyrazole)copper(II) dinitrate, revels that the copper (II) ion is coordinated to two pyrazole nitrogens, one tertiary amine nitrogen of the ligand L and 3,5-dimethylpyrazole, and in the apical position by an alcohol O atom.
Keywords: Structure; copper complex; tripod; pyrazole; tridentate ligand Structure; copper complex; tripod; pyrazole; tridentate ligand
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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El Kodadi, M.; Malek, F.; Touzani, R.; Ramdani, A.; El Kadiri, S.; Eddike, D. Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate. Molecules 2003, 8, 780-787.

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