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Molecules 2002, 7(2), 252-263; doi:10.3390/70200252
Article

Reactivity of 3-Ethoxycarbonyl Isoquinolinium Salts Towards Various Nucleophilic Reagents: Applications to the Synthesis of New 1,2-Dihydroisoquinoline-3-carboxylates

 and *
Received: 16 January 2002 / Revised: 19 February 2002 / Accepted: 20 February 2002 / Published: 28 February 2002
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Abstract

Different types of novel 1,2-disubstituted 1,2-dihydro isoquinolines were synthesized by addition reactions of organolithium, alcoholates and borohydride reagents with various isoquinolinium salts. The leaving group character of the isoquinoline moiety was also evidenced.
Keywords: 1; 2-dihydro isoquinoline; lipophilic isoquinolinium; solvent-free quaternization; organolithium; alcoholate; N; O-acetal; domino reaction 1; 2-dihydro isoquinoline; lipophilic isoquinolinium; solvent-free quaternization; organolithium; alcoholate; N; O-acetal; domino reaction
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Meziane, M.A.A.A.; Bazureau, J.P. Reactivity of 3-Ethoxycarbonyl Isoquinolinium Salts Towards Various Nucleophilic Reagents: Applications to the Synthesis of New 1,2-Dihydroisoquinoline-3-carboxylates. Molecules 2002, 7, 252-263.

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