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Molecules 2002, 7(10), 751-755; doi:10.3390/71000751
Article
Deprotection of Acetals and Ketals by Silica Sulfuric Acid and Wet SiO2
1
Department of Chemistry, College of Science, Yazd University, Yazd, Iran
2
Department of Chemistry, College of Science, Bu-Ali Sina University, Hamadan 65174, P.O. Box 4135, Iran
3
Department of Chemistry, College of Science, Kashan University, Kashan 51167, Iran
* Author to whom correspondence should be addressed.
Received: 25 October 2001; in revised form: 13 October 2002 / Accepted: 14 October 2002 / Published: 31 October 2002
Abstract: Neat chlorosulfonic acid reacts with silica gel to give silica sulfuric acid in which sulfuric acid is immobilized on the surface of silica gel via covalent bonds. A combination of silica sulfuric acid and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under thermal conditions.
Keywords: Silica sulfuric acid; Deacetalization
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MDPI and ACS Style
Mirjalili, B.F.; Zolfigol, M.A.; Bamoniri, A. Deprotection of Acetals and Ketals by Silica Sulfuric Acid and Wet SiO2. Molecules 2002, 7, 751-755.
AMA StyleMirjalili BF, Zolfigol MA, Bamoniri A. Deprotection of Acetals and Ketals by Silica Sulfuric Acid and Wet SiO2. Molecules. 2002; 7(10):751-755.
Chicago/Turabian StyleMirjalili, BiBi F.; Zolfigol, Mohamad A.; Bamoniri, Abdolhamid. 2002. "Deprotection of Acetals and Ketals by Silica Sulfuric Acid and Wet SiO2." Molecules 7, no. 10: 751-755.
Molecules
EISSN 1420-3049
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