Next Article in Journal
Polymerization Mechanism of α,α’-bis(Tetrahydrothiophenio)-β-xylene Dichloride
Previous Article in Journal
Fluorescence Resonance Energy Transfer Using Spiropyran and Diarylethene Photochromic Acceptors
Molecules 2000, 5(3), 594-595; doi:10.3390/50300594

Stereoselective Synthesis of 8-Trialkylstannylmenthols

, ,  and *
Published: 22 March 2000
Download PDF [19 KB, uploaded 18 June 2014]
Abstract: Trialkyltin menthones of type 2 are obtained selectively by 1,4-addition of trialkylstannyl lithium to (-)-pulegone. Reduction of 2 with borane in THF using as catalyst the reagent prepared from borane and (S)-valinol gave a mixture of the corresponding trialkyltin alcohols 3 (Me: 84%; n-Bu: 90,6%) and 4 (Me: 16% and n-Bu: 9,4%).
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |

MDPI and ACS Style

Mandolesi, S.D.; Giagante, N.N.; Dodero, V.; Podestá, J.C. Stereoselective Synthesis of 8-Trialkylstannylmenthols. Molecules 2000, 5, 594-595.

AMA Style

Mandolesi SD, Giagante NN, Dodero V, Podestá JC. Stereoselective Synthesis of 8-Trialkylstannylmenthols. Molecules. 2000; 5(3):594-595.

Chicago/Turabian Style

Mandolesi, Sandra D.; Giagante, Nelda N.; Dodero, Verónica; Podestá, Julio C. 2000. "Stereoselective Synthesis of 8-Trialkylstannylmenthols." Molecules 5, no. 3: 594-595.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert