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Molecules 2000, 5(3), 439-440; doi:10.3390/50300439

Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands

Instituto de Investigaciones en Química Orgánica, Departamento de Química e Ing.Qca., Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina
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Published: 22 March 2000
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Abstract

The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions.
Keywords: tin hydride; vinylstannanes; addition; stereoselectivity; substitution tin hydride; vinylstannanes; addition; stereoselectivity; substitution
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Dodero, V.; Koll, L.C.; Podestá, J.C. Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands. Molecules 2000, 5, 439-440.

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