Molecules 2000, 5(3), 439-440; doi:10.3390/50300439
Article

Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands

,  and * email
Published: 22 March 2000
Download PDF [16 KB, uploaded 18 June 2014]
Abstract: The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions.
Keywords: tin hydride; vinylstannanes; addition; stereoselectivity; substitution
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Dodero, V.; Koll, L.C.; Podestá, J.C. Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands. Molecules 2000, 5, 439-440.

AMA Style

Dodero V, Koll LC, Podestá JC. Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands. Molecules. 2000; 5(3):439-440.

Chicago/Turabian Style

Dodero, V.; Koll, L. C.; Podestá, J. C. 2000. "Synthesis of Ethylenic and Acetylenic Triorganotins with Bulky Organic Ligands." Molecules 5, no. 3: 439-440.


Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert