Next Article in Journal
Previous Article in Journal
Molecules 2000, 5(3), 401-402; doi:10.3390/50300401
Article

Reaction of 2,4-Dinitrochlorobenzene with Aromatic Amines in Toluene: Effect of Nucleophile Structure

1,* , 1, 1, 1 and 2,*
Published: 22 March 2000
Download PDF [16 KB, uploaded 18 June 2014]
Abstract: The kinetics of the reaction of 2,4-dinitrochlorobenzene (DNClB) with aniline and substituted anilines such as p-anisidine, p-toluidine and N-methylaniline have been studied in toluene. Except for N-methylaniline the reactions have shown a third order in amine rate dependence which is consistent with aggregates of the amine acting as the nucleophile. On the other hand, the reaction of DNClB with N-methylaniline under the same conditions shows a linear dependence of the second order rate coefficient, kA, vs [amine], which is consistent with the previous mechanism.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Alvaro, C.E.; Savini, M.C.; Nicotra, V.; Yankelevich, J.S.; Nudelman, N.S. Reaction of 2,4-Dinitrochlorobenzene with Aromatic Amines in Toluene: Effect of Nucleophile Structure. Molecules 2000, 5, 401-402.

AMA Style

Alvaro CE, Savini MC, Nicotra V, Yankelevich JS, Nudelman NS. Reaction of 2,4-Dinitrochlorobenzene with Aromatic Amines in Toluene: Effect of Nucleophile Structure. Molecules. 2000; 5(3):401-402.

Chicago/Turabian Style

Alvaro, C. E.; Savini, M. C.; Nicotra, V.; Yankelevich, J. S.; Nudelman, N. S. 2000. "Reaction of 2,4-Dinitrochlorobenzene with Aromatic Amines in Toluene: Effect of Nucleophile Structure." Molecules 5, no. 3: 401-402.


Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert