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Proceedings of the 12th National Symposium of Organic Chemistry (XII SINAQO), Los Cocos, Cordoba, Argentina, 14-17 November 1999
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DDQ/PbO2: a Novel Oxidation System for Hindered Electron Rich Benzhydrols
Molecules 2000, 5(3), 245-251; doi:10.3390/50300245
Article

Heterocyclic Tricycles as Internal N-Glycosides from 2-Methyl-5-nitro-6-(2-nitrophenyl)-4-phenyl(2-furyl)tetrahydropyranols

1, 2, 1,* , 3,4 and 1
1 Fachbereich Chemie der Universität Rostock, D-18051 Rostock, Germany 2 Institut für Organische Katalyseforschung an der Universität Rostock, Buchbinderstr. 5-6, D-18055 Rostock, Germany 3 Centro Bioactivos Quimicos, Universidad Central de Las Villas, Santa Clara, Cuba 4 Departamento de Farmacia e Bioquimica, Universidade Bandeirante de Sao Paulo (UNIBAN), Rua Maria Candida, 1813 Vila Guilherme Sao Paulo-SP, Brazil
* Author to whom correspondence should be addressed.
Received: 10 February 2000 / Accepted: 14 March 2000 / Published: 16 March 2000
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Abstract

1-Methyl-10-nitro-11-phenyl(2-furyl)-2-aza-13-oxa-tricyclo[7.3.1.03,8]trideca-3,5,7-trienes 3 were synthesized via the reduction of the aromatic 2-nitro group of 2-methyl-5-nitro-6-(2-nitrophenyl)-4-phenyl(2-furyl)tetrahydropyranols 2 and subsequent condensation with their anomeric OH group. As by-products, the corresponding 6-(2-aminophenyl)-2-methyl-5-nitro-4-phenyl(2-furyl)tetrahydropyranols 4 were isolated.
Keywords: pyran derivatives; tricyclo[7.3.1.03; 8]trideca-3; 5; 7-trienes; N-glycosides pyran derivatives; tricyclo[7.3.1.03; 8]trideca-3; 5; 7-trienes; N-glycosides
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Götze, L.; Michalik, M.; Peseke, K.; Quincoces, J.; Reinke, H. Heterocyclic Tricycles as Internal N-Glycosides from 2-Methyl-5-nitro-6-(2-nitrophenyl)-4-phenyl(2-furyl)tetrahydropyranols. Molecules 2000, 5, 245-251.

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