Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion

doi:10.3390/40500126

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Molecules 1999, 4(5), 126-134; doi:10.3390/40500126

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Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion

A. V. Aksenov ¹^,* , I. V. Aksenova ¹, I. V. Borovlev ¹ and Yu. I. Smushkevich ²

¹ Stavropol State University, Chair of Organic Chemistry, 1 Pushkina str, 355009 Stavropol, Russia ² Russian Mendeleev University of Chemical Technology, Chair of Organic Chemistry, 9 Miusskaya sq., 125047 Moscow, Russia

* Author to whom correspondence should be addressed.

Received: 27 January 1998 / Accepted: 8 March 1999 / Published: 26 April 1999

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Abstract: The dianion of 2,3’-biquinolyl with aryl- and hetaryl halides forms the products of arylation to 4’-position, which on treatment with alkyl halides or water yield 1’-alkyl-1’,4’dihydro-2,3’-biquinolyls or 4’-aryl-1’,4’-dihydro-2,3’-biquinolyls respectively. The oxidation of the latter leads to 4’-aryl-2,3’-biquinolyls. The cation dependence of the arylation is shown.

Keywords: Regioselectivity; 2; 3’-biquinolyl dianion

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MDPI and ACS Style

Aksenov, A.V.; Aksenova, I.V.; Borovlev, I.V.; Smushkevich, Y.I. Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion. Molecules 1999, 4, 126-134.

AMA Style

Aksenov A.V., Aksenova I.V., Borovlev I.V., Smushkevich Y.I. Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion. Molecules. 1999; 4(5):126-134.

Chicago/Turabian Style

Aksenov, A. V.; Aksenova, I. V.; Borovlev, I. V.; Smushkevich, Yu. I. 1999. "Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion." Molecules 4, no. 5: 126-134.

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