Molecules 1999, 4(5), 126-134; doi:10.3390/40500126
Article

Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion

1,* email, 1, 1 and 2
Received: 27 January 1998; Accepted: 8 March 1999 / Published: 26 April 1999
Download PDF [32 KB, uploaded 18 June 2014]
Abstract: The dianion of 2,3’-biquinolyl with aryl- and hetaryl halides forms the products of arylation to 4’-position, which on treatment with alkyl halides or water yield 1’-alkyl-1’,4’dihydro-2,3’-biquinolyls or 4’-aryl-1’,4’-dihydro-2,3’-biquinolyls respectively. The oxidation of the latter leads to 4’-aryl-2,3’-biquinolyls. The cation dependence of the arylation is shown.
Keywords: Regioselectivity; 2; 3’-biquinolyl dianion
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Aksenov, A.V.; Aksenova, I.V.; Borovlev, I.V.; Smushkevich, Y.I. Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion. Molecules 1999, 4, 126-134.

AMA Style

Aksenov AV, Aksenova IV, Borovlev IV, Smushkevich YI. Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion. Molecules. 1999; 4(5):126-134.

Chicago/Turabian Style

Aksenov, A. V.; Aksenova, I. V.; Borovlev, I. V.; Smushkevich, Yu. I. 1999. "Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion." Molecules 4, no. 5: 126-134.


Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert