Next Article in Journal
Synthesis of Aromatic Vinyl Esters by Exchange Reaction Catalyzed with Pd(II)
Previous Article in Journal
Professor Ta-shue Chou (1950-1999)
Article Menu

Export Article

Open AccessArticle
Molecules 1999, 4(5), 126-134; doi:10.3390/40500126

Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion

Stavropol State University, Chair of Organic Chemistry, 1 Pushkina str, 355009 Stavropol, Russia
Russian Mendeleev University of Chemical Technology, Chair of Organic Chemistry, 9 Miusskaya sq., 125047 Moscow, Russia
Author to whom correspondence should be addressed.
Received: 27 January 1998 / Accepted: 8 March 1999 / Published: 26 April 1999
View Full-Text   |   Download PDF [32 KB, uploaded 18 June 2014]   |  


The dianion of 2,3’-biquinolyl with aryl- and hetaryl halides forms the products of arylation to 4’-position, which on treatment with alkyl halides or water yield 1’-alkyl-1’,4’dihydro-2,3’-biquinolyls or 4’-aryl-1’,4’-dihydro-2,3’-biquinolyls respectively. The oxidation of the latter leads to 4’-aryl-2,3’-biquinolyls. The cation dependence of the arylation is shown. View Full-Text
Keywords: Regioselectivity; 2; 3’-biquinolyl dianion Regioselectivity; 2; 3’-biquinolyl dianion

Figure 1

This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Aksenov, A.V.; Aksenova, I.V.; Borovlev, I.V.; Smushkevich, Y.I. Regioselectivity of Arylation of 2,3’-Biquinolyl Dianion. Molecules 1999, 4, 126-134.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics



[Return to top]
Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top