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Molecules 2017, 22(9), 1580; doi:10.3390/molecules22091580

Efficient Approach to Carbinol Derivatives through Palladium-Catalyzed Base-Free Addition of Aryltriolborates to Aldehydes

College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325035, China
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Received: 27 August 2017 / Revised: 15 September 2017 / Accepted: 20 September 2017 / Published: 20 September 2017
(This article belongs to the Section Organic Synthesis)
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Abstract

Palladium-catalyzed base-free addition of aryltriolborates to aldehydes has been developed, leading to a wide range of carbinol derivatives in good to excellent yields. The efficiency of this transformation was demonstrated by compatibility with a wide range of functional groups. The present synthetic route to carbinol derivatives could be readily scaled up to gram quantity without difficulty. Thus, this method represents a simple and practical procedure to access carbinol derivatives. View Full-Text
Keywords: palladium-catalyzed; base-free; carbinol derivatives; aryltriolborates; aldehydes palladium-catalyzed; base-free; carbinol derivatives; aryltriolborates; aldehydes
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Hu, K.; Ye, P.; Zhen, Q.; Yao, X.; Xu, T.; Shao, Y.; Chen, J. Efficient Approach to Carbinol Derivatives through Palladium-Catalyzed Base-Free Addition of Aryltriolborates to Aldehydes. Molecules 2017, 22, 1580.

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