Molecules 1997, 2(5), 80-86; doi:10.3390/20500080
Article

The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format

2,* email, 1 and 2
Received: 8 April 1997; Accepted: 18 April 1997 / Published: 15 May 1997
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Two 1,3,8,10-undecatetraenes were synthesized to test the viability of the intramolecular radical cation induced Diels-Alder reaction in the diene - diene format. Cyclization was successful only for the substituted tetraene with the lower oxidation potential. The major hexahydroindene product possessed a trans ring juncture demonstrating a selectivity for the endo stereochemistry.
Keywords: Radical cation; Diels-Alder reaction; intramolecular cyclization
PDF Full-text Download PDF Full-Text [36 KB, uploaded 18 June 2014 19:25 CEST]

Export to BibTeX |
EndNote


MDPI and ACS Style

Rusterholz, D.B.; Gorman, D.B.; Gassman, P.G. The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format. Molecules 1997, 2, 80-86.

AMA Style

Rusterholz DB, Gorman DB, Gassman PG. The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format. Molecules. 1997; 2(5):80-86.

Chicago/Turabian Style

Rusterholz, David B.; Gorman, David B.; Gassman, Paul G. 1997. "The Intramolecular Radical Cation Induced Diels-Alder Reaction in the Diene - Diene Format." Molecules 2, no. 5: 80-86.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert