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Molecules 1997, 2(1), 11-16; doi:10.3390/jan97p4

Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China
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Received: 5 December 1996 / Accepted: 15 January 1997 / Published: 29 January 1997
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Abstract

Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction. A photoinduced electron-transfer mechanism is proposed. View Full-Text
Keywords: Photochemistry; pentafluoroiodobenzene; alkene; single electron-transfer; free radical inhibitor Photochemistry; pentafluoroiodobenzene; alkene; single electron-transfer; free radical inhibitor
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Cao, P.; Long, Z.-Y.; Chen, Q.-Y. Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes. Molecules 1997, 2, 11-16.

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