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Molecules 1997, 2(1), 11-16; doi:10.3390/jan97p4
Article

Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes

,  and *
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China
* Author to whom correspondence should be addressed.
Received: 5 December 1996 / Accepted: 15 January 1997 / Published: 29 January 1997
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Abstract

Irradiation of pentafluoroiodobenzene and alkenes gave the corresponding adducts. The presence of single electron-transfer scavengers, (p-dinitrobenzene and t-Bu2NO) and the free radical inhibitor (hydroquinone) suppressed the reaction. A photoinduced electron-transfer mechanism is proposed.
Keywords: Photochemistry; pentafluoroiodobenzene; alkene; single electron-transfer; free radical inhibitor Photochemistry; pentafluoroiodobenzene; alkene; single electron-transfer; free radical inhibitor
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Cao, P.; Long, Z.-Y.; Chen, Q.-Y. Photoinduced Electron-transfer Reaction of Pentafluoroiodobenzene with Alkenes. Molecules 1997, 2, 11-16.

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