Molecules 2014, 19(2), 2602-2611; doi:10.3390/molecules19022602

Glycosylation of a Newly Functionalized Orthoester Derivative

, ,  and *
Received: 26 January 2014; in revised form: 20 February 2014 / Accepted: 21 February 2014 / Published: 24 February 2014
(This article belongs to the Section Organic Synthesis)
View Full-Text   |   Download PDF [250 KB, uploaded 18 June 2014]
Abstract: Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation.
Keywords: glycosylation; orthoester; electrogenerated acid (EGA); Fmoc group; selective deprotection
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |

MDPI and ACS Style

Kawa, K.; Saitoh, T.; Kaji, E.; Nishiyama, S. Glycosylation of a Newly Functionalized Orthoester Derivative. Molecules 2014, 19, 2602-2611.

AMA Style

Kawa K, Saitoh T, Kaji E, Nishiyama S. Glycosylation of a Newly Functionalized Orthoester Derivative. Molecules. 2014; 19(2):2602-2611.

Chicago/Turabian Style

Kawa, Kohei; Saitoh, Tsuyoshi; Kaji, Eisuke; Nishiyama, Shigeru. 2014. "Glycosylation of a Newly Functionalized Orthoester Derivative." Molecules 19, no. 2: 2602-2611.

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert