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Molecules 2014, 19(12), 21022-21033; doi:10.3390/molecules191221022

Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups

Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, Göttingen 37077, Germany
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Received: 24 October 2014 / Revised: 7 December 2014 / Accepted: 8 December 2014 / Published: 15 December 2014
(This article belongs to the Section Organic Synthesis)
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Abstract

A series of various readily water soluble esters were synthesized by a very efficient procedure. These compounds can be useful as thermosensitive tracers for studying the cooling progress in a low enthalpy georeservoir exploitable by double flash geothermal power plant systems. The kinetics of their hydrolysis was investigated. Acylation of primary alcohols or phenols was carried out by a method based on a single-phase solvent system consisting of ethyl acetate acting as an organic solvent and triethylamine acting as a catalyst. Products were characterized by 1H-NMR, and 13C-NMR. View Full-Text
Keywords: sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics sulfonic acid esters; primary alcohols; phenols; acylation; reaction kinetics
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Idzik, K.R.; Nödler, K.; Maier, F.; Licha, T. Efficient Synthesis and Reaction Kinetics of Readily Water Soluble Esters Containing Sulfonic Groups. Molecules 2014, 19, 21022-21033.

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