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A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties
State Key Laboratory on Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun 130012, China
Department of Chemistry, Northeast Normal University, Changchun 130024, China
* Authors to whom correspondence should be addressed.
Received: 30 January 2013; in revised form: 7 April 2013 / Accepted: 8 April 2013 / Published: 19 April 2013
Abstract: We report here the preparation of asymmetrical phthalocyanine dimers 1a–3a, which are endowed with novel charge transfer bands at 1,151–1,154 nm and strong NIR luminescences at 840–860 nm and 1,600–1,650 nm. Through H-bonding interaction, 1a–3a are inclined to self-assemble into hexrod nanotubes at the interface of CHCl3 and CH3OH. Our results provide further insights into the interaction in molecular dimers, and suggest that 1a–3a have potential application in magnets and supramolecular architectures.
Keywords: organic green dyes; syethesis; NIR-absorption; NIR luminescence; 1-D hexrod nanotubes
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MDPI and ACS Style
Huang, G.; Li, J.; Cong, F.; Li, C.; Chu, X.; Meng, Y.; Du, G.; Du, X. A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties. Molecules 2013, 18, 4628-4639.
Huang G, Li J, Cong F, Li C, Chu X, Meng Y, Du G, Du X. A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties. Molecules. 2013; 18(4):4628-4639.
Huang, Guoqing; Li, Jianxi; Cong, Fangdi; Li, Chao; Chu, Xixi; Meng, Yanyan; Du, Guotong; Du, Xiguang. 2013. "A Series of Asymmetrical Phthalocyanines: Synthesis and Near Infrared Properties." Molecules 18, no. 4: 4628-4639.