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Molecules 2012, 17(9), 11103-11112; doi:10.3390/molecules170911103
Communication

A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization

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 and 1,2,*
Received: 1 August 2012; in revised form: 2 September 2012 / Accepted: 6 September 2012 / Published: 14 September 2012
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Abstract: Assembly of 4,4'-oxybis(benzoic acid) (H2L) with manganese chloride in the presence of 2,2'-biphenyl (2,2'-bpy) affords a new coordination polymer [Mn3L3(2,2'-bpy)2]n (1), in which the [MnL2]n layers are extended by L bridges resulting in a three-dimensional (3-D) coordination framework. The network structure of 1 has unusual (2,6)-connectivity and represents a new type of (812·123)(8)(3) topology. These identical and complementary networks are entangled to generate a self-penetrating supramolecular lattice. Moreover, the fluorescence spectrum of 1 exhibits fluorescent emission in the solution of methanol at room temperature. Electrochemical investigation illustrates the electrochemical properties of the title compound. The structure (C62H40Mn3N4O15)n is monoclinic with a = 14.2304(18), b = 17.019(2), c = 25.805(3) Å, α = γ = 90, β = 92.932(2)° and space group C2/c.
Keywords: (3-D) coordination framework; 4,4'-oxybis(benzoic acid); self-penetrating topology; fluorescence; electrochemical properties (3-D) coordination framework; 4,4'-oxybis(benzoic acid); self-penetrating topology; fluorescence; electrochemical properties
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Diao, K.-S.; Li, L.; Ding, Y.-Q.; Lei, F.-H. A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization. Molecules 2012, 17, 11103-11112.

AMA Style

Diao K-S, Li L, Ding Y-Q, Lei F-H. A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization. Molecules. 2012; 17(9):11103-11112.

Chicago/Turabian Style

Diao, Kai-Sheng; Li, Long; Ding, Yu-Qiu; Lei, Fu-Hou. 2012. "A 3-D Metal-Organic Framework Constructed with Manganese(ΙΙ), 4,4'-Oxybis(benzoic acid) and 2,2'-Biphenyl: Synthesis, Crystal Structure and Photoelectric Property Characterization." Molecules 17, no. 9: 11103-11112.


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