Next Article in Journal
Synthesis and Field Evaluation of the Sex Pheromone Analogues to Soybean Pod Borer Leguminivora glycinivorella
Previous Article in Journal
Acetylated and Methylated β-Cyclodextrins as Viable Soluble Supports for the Synthesis of Short 2′-Oligodeoxyribo-nucleotides in Solution
Article Menu

Export Article

Open AccessArticle
Molecules 2012, 17(10), 12121-12139; doi:10.3390/molecules171012121

Suzuki-Miyaura Reactions Catalyzed by C2-Symmetric Pd-Multi-Dentate N-Heterocyclic Carbene Complexes

1
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
2
College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
*
Authors to whom correspondence should be addressed.
Received: 20 September 2012 / Revised: 6 October 2012 / Accepted: 9 October 2012 / Published: 16 October 2012
View Full-Text   |   Download PDF [390 KB, uploaded 18 June 2014]   |  

Abstract

Suzuki-Miyaura coupling reactions are promoted by Pd complexes ligated with C2-symmetric multi-dentate N-heterocyclic carbenes derived in situ from Pd(OAc)2 and imidazolium salts. Good to excellent yields were obtained for aryl bromides as substrates. Turnover numbers of up to 105 could be achieved with 5 × 10−4 mol% of Pd(OAc)2/1 × 10−3 mol% NHC precatalyst in 24 h. View Full-Text
Keywords: imidazolium salt; N-heterocyclic carbene; palladium; Suzuki-Miyaura coupling; catalysis imidazolium salt; N-heterocyclic carbene; palladium; Suzuki-Miyaura coupling; catalysis
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Jiang, L.; Shan, F.; Li, Z.; Zhao, D. Suzuki-Miyaura Reactions Catalyzed by C2-Symmetric Pd-Multi-Dentate N-Heterocyclic Carbene Complexes. Molecules 2012, 17, 12121-12139.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]

Molecules EISSN 1420-3049 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top