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Molecules 2011, 16(6), 4615-4631; doi:10.3390/molecules16064615
Article

A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II) Complex: Synthesis, Photophysical and Electrochemical Properties

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Received: 27 April 2011; in revised form: 31 May 2011 / Accepted: 1 June 2011 / Published: 3 June 2011
(This article belongs to the Section Organic Synthesis)
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Abstract: In our quest to develop good materials as photosensitizers for photovoltaic dye-sensitized solar cells (DSSCs), cis-dithiocyanato-4-(2,3-dimethylacrylic acid)-2,2'-bipyridyl-4-(9-anthracenyl-(2,3-dimethylacrylic)-2,2'-bipyridyl ruthenium(II) complex, a high molar extinction coefficient charge transfer sensitizer, was designed, synthesized and characterized by spectroscopy and electrochemical techniques. Earlier studies on heteroleptic ruthenium(II) complex analogues containing functionalized oligo-anthracenyl phenanthroline ligands have been reported and documented. Based on a general linear correlation between increase in the length of π-conjugation bond and the molar extinction coefficients, herein, we report the photophysical and electrochemical properties of a Ru(II) bipyridyl complex analogue with a single functionalized anthracenyl unit. Interestingly, the complex shows better broad and intense metal-to ligand charge transfer (MLCT) band absorption with higher molar extinction coefficient (λmax = 518 nm, e = 44900 M−1cm−1), and appreciable photoluminescence spanning the visible region than those containing higher anthracenyl units. It was shown that molar absorption coefficient of the complexes may not be solely depended on the extended π-conjugation but are reduced by molecular aggregation in the molecules.
Keywords: Ru(II) complex; bipyridine; extended π-bond conjugation; spectroscopy; molar extinction coefficient; molecular aggregation Ru(II) complex; bipyridine; extended π-bond conjugation; spectroscopy; molar extinction coefficient; molecular aggregation
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Adeloye, A.O.; Ajibade, P.A. A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II) Complex: Synthesis, Photophysical and Electrochemical Properties. Molecules 2011, 16, 4615-4631.

AMA Style

Adeloye AO, Ajibade PA. A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II) Complex: Synthesis, Photophysical and Electrochemical Properties. Molecules. 2011; 16(6):4615-4631.

Chicago/Turabian Style

Adeloye, Adewale O.; Ajibade, Peter A. 2011. "A High Molar Extinction Coefficient Mono-Anthracenyl Bipyridyl Heteroleptic Ruthenium(II) Complex: Synthesis, Photophysical and Electrochemical Properties." Molecules 16, no. 6: 4615-4631.


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