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Molecules 2008, 13(11), 2837-2847; doi:10.3390/molecules131102837
Article

Microwave Accelerated Aza-Claisen Rearrangement

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Received: 7 October 2008; in revised form: 28 October 2008 / Accepted: 4 November 2008 / Published: 14 November 2008
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Abstract: A study of microwave-induced and standard thermal Overman rearrangement of selected allylic trichloroacetimidates 1a-1f, 6-8 to the corresponding acetamides 2a-2f, 9-11 is reported. The microwave-assisted rearrangement of trifluoroacetimidate 13 is also described. Using this methodology, an efficient access to versatile allylic trihaloacetamides building synthons was established.
Keywords: Overman rearrangement; Imidate; Microwave irradiation Overman rearrangement; Imidate; Microwave irradiation
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Gajdošíková, E.; Martinková, M.; Gonda, J.; Conka, P. Microwave Accelerated Aza-Claisen Rearrangement. Molecules 2008, 13, 2837-2847.

AMA Style

Gajdošíková E, Martinková M, Gonda J, Conka P. Microwave Accelerated Aza-Claisen Rearrangement. Molecules. 2008; 13(11):2837-2847.

Chicago/Turabian Style

Gajdošíková, Eva; Martinková, Miroslava; Gonda, Jozef; Conka, Patrik. 2008. "Microwave Accelerated Aza-Claisen Rearrangement." Molecules 13, no. 11: 2837-2847.


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