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Polymer – Supported Cobalt (II) Catalysts for the Oxidation of Alkenes
Department of Polymer Science and Technology, Krakow University of Technology, ul. Warszawska 24, 31-155 Krakow, Poland
* Author to whom correspondence should be addressed.
Received: 16 February 2005; in revised form: 5 December 2005 / Accepted: 5 December 2005 / Published: 31 January 2006
Abstract: Polymer-supported heterogeneous catalysts in a form of complexes of 8-hydroxy- quinoline with cobalt acetate were synthesized. Conjugated polymers – polyaniline (PANI), poly-o-toluidine (POT), poly-o-anisidine (POA) – were used as supports. Oxidation reactions of aliphatic and aromatic hydrocarbons were carried out in the presence of molecular oxygen at atmospheric pressure and epoxides or ketones were obtained as the main products with high selectivity.
Keywords: Epoxidation; cobalt complexes; polyaniline based-catalysts; conjugated- polymers; catalysts.
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MDPI and ACS Style
Błaż, E.; Pielichowski, J. Polymer – Supported Cobalt (II) Catalysts for the Oxidation of Alkenes. Molecules 2006, 11, 115-120.
Błaż E, Pielichowski J. Polymer – Supported Cobalt (II) Catalysts for the Oxidation of Alkenes. Molecules. 2006; 11(1):115-120.
Błaż, Edyta; Pielichowski, Jan. 2006. "Polymer – Supported Cobalt (II) Catalysts for the Oxidation of Alkenes." Molecules 11, no. 1: 115-120.