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Molecules 2005, 10(8), 901-911; doi:10.3390/10080901
Article

Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

 and *
Received: 2 January 2005 / Accepted: 5 January 2005 / Published: 31 August 2005
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Abstract

Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2.
Keywords: Glycosidase inhibitor; Ferrier-II reaction; palladium chloride. Glycosidase inhibitor; Ferrier-II reaction; palladium chloride.
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Takahashi, H.; Ikegami, S. Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement. Molecules 2005, 10, 901-911.

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