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Molecules 2005, 10(8), 901-911; doi:10.3390/10080901
Article

Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

 and *
Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Japan
* Author to whom correspondence should be addressed.
Received: 2 January 2005 / Accepted: 5 January 2005 / Published: 31 August 2005
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Abstract

Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl2.
Keywords: Glycosidase inhibitor; Ferrier-II reaction; palladium chloride. Glycosidase inhibitor; Ferrier-II reaction; palladium chloride.
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Takahashi, H.; Ikegami, S. Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement. Molecules 2005, 10, 901-911.

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