Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

doi:10.3390/10080901

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Molecules 2005, 10(8), 901-911; doi:10.3390/10080901

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Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement

H. Takahashi and S. Ikegami*

Faculty of Pharmaceutical Sciences, Teikyo University, Sagamiko, Japan

* Author to whom correspondence should be addressed.

Received: 2 January 2005 / Accepted: 5 January 2005 / Published: 31 August 2005

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Abstract: Cyclophellitol and its C3-epimer have been synthesized from5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeletonwas constructed through a Ferrier-II reaction meditated by PdCl₂.

Keywords: Glycosidase inhibitor; Ferrier-II reaction; palladium chloride.

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MDPI and ACS Style

Takahashi, H.; Ikegami, S. Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement. Molecules 2005, 10, 901-911.

AMA Style

Takahashi H, Ikegami S. Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement. Molecules. 2005; 10(8):901-911.

Chicago/Turabian Style

Takahashi, H.; Ikegami, S. 2005. "Synthesis of Cyclophellitol Utilizing a Palladium Chloride Mediated-Ferrier-II Rearrangement." Molecules 10, no. 8: 901-911.

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