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Entropy 2003, 5(4), 348-356; doi:10.3390/e5040348
Article

Behavior of the Thermodynamic Properties of Binary Mixtures near the Critical Azeotrope

Faculté des Sciences, Département de Chimie, Université Badji Mokhtar, B.P.12, El-Hadjar, Annaba (23200), Algeria
Received: 26 September 2003 / Accepted: 19 December 2003 / Published: 22 December 2003
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Abstract

In this work we investigate the critical line of binary azeotropic mixtures of acetone-n-pentane. We pinpoint the abnormal behavior of the critical density line as a function of the mole fraction of one of the component and show its influence on other thermodynamic properties such as the volume, the enthalpy and the entropy.
Keywords: azeotropic mixtures; critical line; mole fraction; equation of state azeotropic mixtures; critical line; mole fraction; equation of state
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Abbaci, A. Behavior of the Thermodynamic Properties of Binary Mixtures near the Critical Azeotrope. Entropy 2003, 5, 348-356.

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