The paper studies the properties of brass workpieces for antifriction rings under severe plastic deformation by high-pressure torsion. The evolution of microstructure and mechanical properties of deformed workpieces after six cycles of deformation by high-pressure torsion at 500 °C have been studied. All metallographic studies were performed using modern methods: transmission electron microscopy (TEM) and analysis electron back scatter diffraction patterns (EBSD). The deformation resulted in an ultrafine grained structure with a large number of large-angle boundaries. The strength properties of brass increased compared to the initial state almost by three times, the microhardness also increases by three times, i.e., increased from 820 MPa in the initial state to 2115 MPa after deformation. In this case, the greatest increase in strength properties occurs in the first two cycles of deformation. Full article

This article presents research on selected physical and mechanical properties of cement-based plasters and masonry mortars with consistency-improving additives, namely, traditional hydrated lime and a plasticizing and aerating mixture (APA), which, in practice, is often considered to be a lime substitute. Comparative analysis of the properties of mortars with alternative additives—lime or APA—was carried out, taking into consideration possible effects of cement, as two types of Portland cement were used for the research. For fresh mortar, mixture consistency, air content, resistance to segregation, and water retention were determined. Tests on hardened mortars included tests of porosity and impermeability, depth of penetration of water under pressure, drying shrinkage, as well as compressive and bending strength, modulus of elasticity, and adhesion of mortars to the base. In addition, research has shown that cement–lime mortars and cement mortars with APA admixture of similar consistency in the fresh state are characterized by significantly different properties. The results show, in most of the features analyzed, more favorable properties of mortars with the use of traditional lime. For shrinkage only, the use of admixture turned out to be more advantageous. Full article

Car clutch facings are complex fiber-reinforced composites. The coefficient of thermal expansion (CTE) of the composite is one of the main thermal properties, which affects dry clutch engagement process due to heat associated with friction. In the case of clutch facing, which only exists in its final form as a non-planar annular disc, it is difficult to define an elementary representative volume. The objective of this work was to develop a method for identifying the CTE distributions on the entire part. A device allowing measuring the strain fields by digital image correlation (DIC) under homogeneous thermal loading (up to 300 °C) was developed. The experimental results highlight the heterogeneity and the orthotropic nature of the material behavior and the influence of the angle between the fibers on the CTE. To take into account that the measured strain fields are related to the CTE, but also to the shape of the part, different approaches to identify the CTE were considered: direct measurements, classical laminate theory (CLT) and finite element method updating (FEMU). Only the FEMU allows an accurate identification of the CTE distributions. Nevertheless, the CLT respects the orders of magnitude and remains a useful tool for the design of clutches. Full article

In the current work, a core-shell type exchange coupled composite structure was constructed by micromagnetic simulation with a phase FePt core and an iron shell. Four types of switching loops with magnetic domain structure evolution were demonstrated. Based on the simulation results, a switching type diagram was constructed, which displays various hysteresis loops as a function of core radius and shell thickness. Furthermore, the effects of switching type and composite structure on the coercivity and remanent magnetization were predicted and discussed. This finding indicates that core-shell type FePt/Fe composite structure film has a large advantage in designing exchange-coupled bit patterned media to realize high-density storage devices at the nanoscale. Full article

It is a common practice to add rheology modifiers to functional inks, such as graphene inks, to optimize the rheological properties so that they can be printed with a certain printing technique. This practice may lead to inks formulations with poorer electrical, optical, and mechanical performance upon its application, which are of paramount importance in printed electronics. In this study, we demonstrate for three different commercial graphene-based inks that it is possible to control the amount of ink transferred to the flat surface by tweaking printing parameters, such as the velocity and the length scale of the gravure cell, without modifying the rheology of the ink. Finally, the results are summarized in printing maps based on dimensionless numbers, namely, the capillary and Reynolds numbers. Full article

The development of ceramic materials resistance in various aggressive media combined with required mechanical properties is of considerable importance for enabling the wider application of ceramics. The corrosion resistance of ceramic materials depends on their purity and microstructure, the kind of aggressive media used and the ambient temperature. Therefore, the corrosion resistance of alumina ceramics in aqueous HNO₃ solutions of concentrations of 0.50 mol dm⁻³, 1.25 mol dm⁻³ and 2.00 mol dm⁻³ and different exposure times—up to 10 days—have been studied. The influence of temperature (25, 40 and 55 °C) was also monitored. The evaluation of Al₂O₃ ceramics corrosion resistance was based on the concentration measurements of eluted Al³⁺, Ca²⁺, Fe³⁺, Mg²⁺, Na⁺ and Si⁴⁺ ions obtained by inductively coupled plasma atomic emission spectrometry (ICP-AES), as well as density measurements of the investigated alumina ceramics. The response surface methodology (RSM) was used for the optimization of parameters within the experimental “sample-corrosive media” area. The exposure of alumina ceramics to aqueous HNO₃ solutions was conducted according to the Box–Behnken design. After the regression functions were defined, conditions to achieve the maximum corrosion resistance of the sintered ceramics were determined by optimization within the experimental area. Full article

We propose obtaining TiO₂ films by ICPCVD for the fabrication of low-loss waveguides. The challenge is to produce a dense and homogeneous layer with a high refractive index and low absorption in the visible range. Crystallized layers with features such as grains and amorphous layers have a rather low index for the application targeted, so we aimed for an intermediate state. We investigated the influence of plasma power, pressure, deposition time and annealing temperature on the structural, crystalline, and optical properties in order to tailor them. We showed that crystallization into rutile at the nanoscale occurred during deposition and under wisely chosen conditions, we reached a refractive index of 2.5 at 630 nm without creating interfaces or inhomogeneity in the layer depth. Annealing permits one to further increase the index, up to 2.6. TEM analysis on one sample before and after annealing confirmed the nano-polycrystallization and presence of both anatase and rutile phases and we considered that this intermediate state of crystallization was the best compromise for guided optics. Full article

LuAG:Ce (Lu₃Al₅O₁₂:Ce) is one of the most important color converters in white lighting industry. Especially, LuAG:Ce film attracts more attention due to the outstanding advantages, such as the efficient heat dissipation, the saving of rare earth, and so on. Here, LuAG:Ce film on sapphire was successfully prepared by the ultrasonic spray pyrolysis process. The phase, microstructure and photoluminescence of LuAG:Ce films were investigated. LuAG:Ce films had a thickness of around 5 μm, which were well crystallized at 1000 °C in air atmosphere to form the typical garnet structure. Under the protection of CO atmosphere, increasing the annealing temperature greatly enhanced the photoluminescence performance. After annealing at 1500 °C for 5 h in CO atmosphere, 3.0 mol.% Ce³⁺ doped LuAG:Ce film exhibited the highest emission and excitation intensity. The emission intensity of 3.0 mol.% Ce³⁺ doped LuAG:Ce film annealed at 1500 °C in CO atmosphere increased up to five times, when compared with the best LuAG:Ce film annealed at 1000 °C in air atmosphere. The effects of Ce³⁺ doping concentration on the photoluminescence were also examined. As the Ce³⁺ doping concentration increased from 0.2 mol.% to 7.0 mol.%, the color of LuAG:Ce films changed from yellowish green to greenish yellow. When coupling the 3.0 mol.% Ce³⁺ doped LuAG:Ce film with a 0.5 W 450 nm blue laser, the formed device successfully emitted white light. Full article

This paper aims to study the suitability of partial replacement of lime by waste originating from the cleaning of flue gases from the combustion of industrial wastes in the production of autoclaved aerated concrete (AAC). The compressive strength, bulk density, pore structure, phase composition, and microstructure of hydration products of the AAC were analyzed. According to the results, the addition of the waste can effectively enhance the mechanical properties of AAC due to the differences in morphology of hydration product—1.1 nm tobermorite and related dense microstructure. The pore size distribution was significantly influenced by waste addition, which was one of the main reasons for the increase in thermal conductivity. The XRD and SEM results showed that foreign ions introduced with the wastes affect the synthesis of 1.1 nm tobermorite. Moreover, it was shown that waste containing a high content of CaO can be used as lime replacement, which allows reducing CO₂ emissions during the AAC production process. Full article

Porous tantalum has been extensively used in orthopaedic surgery, including uncemented total knee arthroplasty (TKA). Favourable results were reported with earlier monobloc tibial components and the design evolved to modular implants. We aimed to analyse possible causes for extensive medial tibia bone loss, resulting in modular porous tantalum tibia baseplate fracture after primary TKA. Retrieved tissue samples were scanned with 3 MeV focused proton beam for Proton-Induced X-ray Emission (micro-PIXE) elemental analysis. Fractographic and microstructural analysis were performed by stereomicroscopy. A full 3D finite-element model was made for numerical analysis of stress–strain conditions of the tibial baseplate. Histological examination of tissue underneath the broken part of the tibial baseplate revealed dark-stained metal debris, which was confirmed by micro-PIXE to consist of tantalum and titanium. Fractographic analysis and tensile testing showed that the failure of the tibial baseplate fulfilled the criteria of a typical fatigue fracture. Microstructural analysis of the contact surface revealed signs of bone ingrowth in 22.5% of the surface only and was even less pronounced in the medial half of the tibial baseplate. Further studies are needed to confirm the responsibility of metal debris for an increased bone absorption leading to catastrophic tibial tray failure. Full article

Spontaneous metallic Pb whisker formation from Pb and Bi containing Al-alloy’s surfaces is a newly discovered phenomenon. The whiskers display unique formations, growth and morphology, which give the opportunity to be applied for specialized sensor and electronics applications. Within this work, the impact of environmental conditions (gas composition and moisture) is investigated and correlated with the modification of whisker evolution and growth dynamics. Furthermore, the residual stress state of the aluminum matrix using deep cryogenic treatment is modified and used to further increase whisker nucleation and growth by up to three- and seven-fold, respectively, supported by quantitative results. The results of this paper indicate the possibility to manipulate the whisker not only in terms of their kinetics but also their morphology (optimal conditions are 20% O₂ and 35% humidity). Such features allow the tailoring of the whisker structure and surface to volume ratio, which can be optimized for different applications. Finally, this research provides new insight into the growth dynamics of the whiskers through in situ and ex situ measurements, providing further evidence of the complex nucleation and growth mechanisms that dictate the spontaneous growth of Pb whiskers from Al-alloy 6026 surfaces with growth velocities up to 1.15 µm/s. Full article

This work studies the influence of loading velocity and previous cyclic loading history on the stiffness and strength of a multifilament coreless ultra-high-molecular-weight polyethylene (UHMWPE) surgical suture. Thread samples (n = 8) were subjected to a load-to-failure test at 0.1, 0.5, 1, 5, and 10 mm/s without previous loading history and after 10 cycles of loading at 1–10 N, 1–30 N, and 1–50 N. The experimental data were fitted to mathematical models to compute the stress–strain relation and the strength of the suture. The bilinear model involving two stress–strain ratios for low- and high-strain intervals was the best fit. The ratio in the low-strain range rose with loading speed, showing mean increases of 5.9%, 6.5%, 7.9%, and 7.3% between successive loading speeds. Without a previous loading history, this ratio was less than half than that at high strain. However, 10 cycles of 1–30 N or 1–50 N significantly increased the stress–strain ratio at a low strain level by 135% and 228%, respectively. The effect persisted after 2 min but vanished after 24 h. No influence was found on the suture strength. In conclusion, the stiffness of the studied suture was influenced by the strain level, loading velocity, and recent cyclic loading history. Conversely, the suture strength was not affected. Full article

Creating biofunctional artificial scaffolds could potentially meet the demand of patients suffering from bone defects without having to rely on donors or autologous transplantation. Three-dimensional (3D) printing has emerged as a promising tool to fabricate, by computer design, biodegradable polymeric scaffolds with high precision and accuracy, using patient-specific anatomical data. Achieving controlled degradation profiles of 3D printed polymeric scaffolds is an essential feature to consider to match them with the tissue regeneration rate. Thus, achieving a thorough characterization of the biomaterial degradation kinetics in physiological conditions is needed. Here, 50:50 blends made of poly($\epsilon$-caprolactone)–Poly(D,L-lactic-co-glycolic acid (PCL-PLGA) were used to fabricate cylindrical scaffolds by 3D printing (⌀ 7 × 2 mm). Their hydrolytic degradation under static and dynamic conditions was characterized and quantified. For this purpose, we designed and in-house fabricated a customized bioreactor. Several techniques were used to characterize the degradation of the parent polymers: X-ray Photoelectron Spectroscopy (XPS), Gel Permeation Chromatography (GPC), Scanning Electron Microscopy (SEM), evaluation of the mechanical properties, weigh loss measurements as well as the monitoring of the degradation media pH. Our results showed that flow perfusion is critical in the degradation process of PCL-PLGA based scaffolds implying an accelerated hydrolysis compared to the ones studied under static conditions, and up to 4 weeks are needed to observe significant degradation in polyester scaffolds of this size and chemical composition. Our degradation study and characterization methodology are relevant for an accurate design and to tailor the physicochemical properties of polyester-based scaffolds for bone tissue engineering. Full article

It is often observed that thermal stress enhances crack propagation in materials, and, conversely, crack propagation can contribute to temperature shifts in materials. In this study, we first consider the thermoelasticity model proposed by M. A. Biot and study its energy dissipation property. The Biot thermoelasticity model takes into account the following effects. Thermal expansion and contraction are caused by temperature changes, and, conversely, temperatures decrease in expanding areas but increase in contracting areas. In addition, we examine its thermomechanical properties through several numerical examples and observe that the stress near a singular point is enhanced by the thermoelastic effect. In the second part, we propose two crack propagation models under thermal stress by coupling a phase field model for crack propagation and the Biot thermoelasticity model and show their variational structures. In our numerical experiments, we investigate how thermal coupling affects the crack speed and shape. In particular, we observe that the lowest temperature appears near the crack tip, and the crack propagation is accelerated by the enhanced thermal stress. Full article

As it is known, beryllium bronze, an important copper alloy, is widely used in the field of aerospace. Since the performance of domestic and imported beryllium bronze alloys have obvious differences, domestic beryllium bronze QBe2.0 and imported C17200 alloy were adopted, and the hardness and tensile properties of imported and domestic beryllium bronze alloys in the peak aging state were compared and analyzed. In addition, the microstructure morphologies of the C17200 alloy and QBe2.0 alloy were analyzed by SEM, EBSD, and TEM. This study adopted a data-driven exploration approach to elaborate the differences between C17200 and QBe2.0 alloy. After aging at 300 °C for 2 h (peak aging), the tensile strengths of the C17200 alloy and QBe2.0 alloy were 1357 MPa and 1309 MPa, the yield strengths were 1195 MPa and 1188 MPa, and the elongations were 5.5% and 4.0%, respectively. In the peak-aged state, the grain size, uniformity, small angle grain boundary, and twin density of the C17200 alloy were much better than those of the QBe2.0 alloy, which led to more significant grain refinement and twin strengthening effects. A large amount of γ’ phase, γ phase, and β phase were precipitated in both alloys, but the precipitation density of the γ’ strengthening phase in the C17200 alloy was much greater than that of the QBe2.0 alloy. The C17200 alloy exhibited better mechanical properties under the combined effects of the various strengthening mechanisms, which provided a guideline for the subsequent improvement of domestic alloys and laid a solid foundation for the development of new copper alloys. Full article