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Inorganics 2015, 3(4), 467-481; doi:10.3390/inorganics3040467

Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis

1
Univ. Lille, CNRS, Ecole Nationale Supérieure de Chimie de Lille, UMR 8181-UCCS—Unité de Catalyse et Chimie du Solide, F-59000 Lille, France
2
Institut Universitaire de France, 75231 Paris, France
*
Author to whom correspondence should be addressed.
Academic Editors: Stephen Mansell and Steve Liddle
Received: 18 September 2015 / Revised: 27 October 2015 / Accepted: 29 October 2015 / Published: 9 November 2015
(This article belongs to the Special Issue Rare Earth and Actinide Complexes)
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Abstract

In this study, we are combining two areas of chemistry; solid-state coordination polymers (or Metal-Organic Framework—MOF) and polymerization catalysis. MOF compounds combining two sets of different lanthanide elements (Nd3+, Eu3+/Tb3+) were used for that purpose: the use of neodymium was required due to its well-known catalytic properties in dienes polymerization. A second lanthanide, europium or terbium, was included in the MOF structure with the aim to provide luminescent properties. Several lanthanides-based MOF meeting these criteria were prepared according to different approaches, and they were further used as catalysts for the polymerization of isoprene. Stereoregular cis-polyisoprene was received, which in some cases exhibited luminescent properties in the UV-visible range. View Full-Text
Keywords: MOF; lanthanide; neodymium; isoprene polymerisation; cis-selective; luminescence MOF; lanthanide; neodymium; isoprene polymerisation; cis-selective; luminescence
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Russell, S.; Loiseau, T.; Volkringer, C.; Visseaux, M. Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis. Inorganics 2015, 3, 467-481.

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