Influence of Alkali Treatment on Anodized Titanium Alloys in Wollastonite Suspension
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Procedures of Surface Treatment
2.2. Characterization of the Anodized Surfaces
2.2.1. Microstructure, Surface Wettability and Roughness
2.2.2. Chemical Composition
3. Results and Discussion
3.1. Microstructure of the Modified Titanium Alloy Surfaces
3.2. Wettability and Surface Roughness
3.3. Chemical Composition Analysis
3.4. XPS Measurement
3.5. Raman Spectroscopy
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Titanium Alloy | Al | Nb | Zr | Ta | Mo | Fe | C | N | H | O | Ti |
---|---|---|---|---|---|---|---|---|---|---|---|
Ti-6Al-7Nb (TAN) | 6.05 | 6.80 | - | 0.35 | - | 0.08 | 0.04 | 0.01 | 0.003 | 0.11 | balance |
Ti-13Nb-13Zr (TNZ) | - | 13.30 | 13.00 | - | - | 0.08 | 0.05 | 0.0009 | 0.005 | 0.10 | |
Ti-15Mo (TM) | - | - | - | - | 14.73 | 0.06 | 0.08 | 0.016 | 0.01 | 0.15 |
Sample | Contact Angle/° | Surface Roughness, μm | ||
---|---|---|---|---|
Ra | Rq | Rz | ||
TM | 47.6 ± 5.7 | 0.28 | 0.36 | 0.30 |
TM-AT | 2.3 ± 0.7 | 1.08 | 2.19 | 309.06 |
TNZ | 120 ± 5.0 | 0.51 | 0.63 | 9.77 |
TNZ-AT | 21.8 ± 4.6 | 2.74 | 3.39 | 168.09 |
TAN | 51.2 ± 4.7 | 0.30 | 0.48 | 1.48 |
TAN-AT | 11.7 ± 2.7 | 2.37 | 2.91 | 92.40 |
Sample | Concentration, at % | ||||||||
---|---|---|---|---|---|---|---|---|---|
Ti | Al | Nb/Mo | Ca | Na | Zr | C | O | Si | |
TM-AT | 17.1 | - | 0.1 | 2.4 | 13.4 | - | 11.1 | 55.3 | 0.6 |
TNZ-AT | 9.5 | - | 0.5 | 3.4 | 6.3 | 0.9 | 27.7 | 50.9 | 0.8 |
TAN-AT | 9.8 | 0.3 | 0.3 | 5.6 | 7.5 | - | 24.6 | 51.4 | 0.5 |
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Kazek-Kęsik, A.; Leśniak, K.; Zhidkov, I.S.; Korotin, D.M.; Kukharenko, A.I.; Cholakh, S.O.; Kalemba-Rec, I.; Suchanek, K.; Kurmaev, E.Z.; Simka, W. Influence of Alkali Treatment on Anodized Titanium Alloys in Wollastonite Suspension. Metals 2017, 7, 322. https://doi.org/10.3390/met7090322
Kazek-Kęsik A, Leśniak K, Zhidkov IS, Korotin DM, Kukharenko AI, Cholakh SO, Kalemba-Rec I, Suchanek K, Kurmaev EZ, Simka W. Influence of Alkali Treatment on Anodized Titanium Alloys in Wollastonite Suspension. Metals. 2017; 7(9):322. https://doi.org/10.3390/met7090322
Chicago/Turabian StyleKazek-Kęsik, Alicja, Katarzyna Leśniak, Ivan S. Zhidkov, Danila M. Korotin, Andrey I. Kukharenko, Seif O. Cholakh, Izabela Kalemba-Rec, Katarzyna Suchanek, Ernst Z. Kurmaev, and Wojciech Simka. 2017. "Influence of Alkali Treatment on Anodized Titanium Alloys in Wollastonite Suspension" Metals 7, no. 9: 322. https://doi.org/10.3390/met7090322