Next Article in Journal
Excellent Performance of Fe78Si9B13 Metallic Glass for Activating Peroxymonosulfate in Degradation of Naphthol Green B
Next Article in Special Issue
Effect of Pyrite on Thiosulfate Leaching of Gold and the Role of Ammonium Alcohol Polyvinyl Phosphate (AAPP)
Previous Article in Journal
In-Situ Investigation of Strain-Induced Martensitic Transformation Kinetics in an Austenitic Stainless Steel by Inductive Measurements
Previous Article in Special Issue
Leaching Kinetics of Hemimorphite in Ammonium Chloride Solution
Article Menu
Issue 7 (July) cover image

Export Article

Open AccessArticle
Metals 2017, 7(7), 272; doi:10.3390/met7070272

An Efficient Approach for Lithium and Aluminum Recovery from Coal Fly Ash by Pre-Desilication and Intensified Acid Leaching Processes

Key Laboratory for Resource Exploration Research of Hebei Province, Hebei University of Engineering, Handan 056038, China
*
Author to whom correspondence should be addressed.
Received: 26 June 2017 / Revised: 10 July 2017 / Accepted: 11 July 2017 / Published: 14 July 2017
(This article belongs to the Special Issue Valuable Metal Recycling)
View Full-Text   |   Download PDF [4646 KB, uploaded 14 July 2017]   |  

Abstract

A novel technique was developed for the recovery of lithium and aluminum from coal fly ash using a combination of pre-desilication and an intensified acid leaching process. The main components of the high-aluminum fly ash were found to be Al2O3 and SiO2, and the Al/Si ratio increased from 1.0 to 1.5 after desiliconization. The lithium content of the coal fly ash met national recycling standards. The optimal acid leaching conditions, under which the leaching efficiencies of lithium and aluminum were 82.23% and 76.72%, respectively, were as follows: 6 mol/L HCl, 1:20 solid to liquid ratio, 120 °C and 4 h. During the hydrochloric acid pressure leaching process, spherical particles of desilicated fly ash were decomposed into flakes. Part of the mullite phase was dissolved, and most of the glass phase leached into the liquor. The generation of the silicates hindered lithium transport, which decreased the leaching rate of lithium. This work suggests that the preprocessing is a promising option for effective recovery of high-aluminum and fly ash-associated lithium. View Full-Text
Keywords: coal fly ash; pre-desilication; acid leaching; lithium; high-aluminum coal fly ash; pre-desilication; acid leaching; lithium; high-aluminum
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Li, S.; Qin, S.; Kang, L.; Liu, J.; Wang, J.; Li, Y. An Efficient Approach for Lithium and Aluminum Recovery from Coal Fly Ash by Pre-Desilication and Intensified Acid Leaching Processes. Metals 2017, 7, 272.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Metals EISSN 2075-4701 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top