Effect of Hydrogen in Mixed Gases on the Mechanical Properties of Steels—Theoretical Background and Review of Test Results
Abstract
:1. Introduction
2. Fugacity of Hydrogen in Gas Mixtures
- P: total pressure,
- R: universal gas constant, 8.314 J/(mol K),
- T: absolute temperature, K,
- Vm: molar volume.
- xHH: molar fraction of H2,
- P: total pressure of the gas mixture,
- b: co-volume constant of the gas mixture.
- pHH, pGas: partial pressures of H2 and the other gas, respectively,
- bHH, bGas: co-volume constants of H2 and the other gas, respectively.
3. Compilation and Interpretation of Literature Results for Mechanical Properties as a Function of Hydrogen Fugacity
3.1. Tensile Tests
3.2. Fracture Toughness Tests
3.3. Fatigue Crack Growth Tests
3.4. General Comments
4. Conclusions
- For materials testing purposes requiring a defined atmosphere, testing in CH4-H2 mixtures is preferred compared to N2-H2 mixtures to simulate the effect of H2 additions to NG.
- The reviewed results imply no significant difference between tests in pure H2 gas and tests in gas mixtures at the same hydrogen fugacity. This needs to be verified experimentally.
- Among the test methods reviewed here, fatigue crack growth testing is the most sensitive method to measure hydrogen effects in pipeline steels even at a very low fugacity (less than 0.5 MPa). Fracture toughness testing appears less sensitive followed by tensile testing, especially with smooth specimens.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Coefficient | N2 | CH4 |
---|---|---|
A, MPa−5 | 0 | −0.00000006 |
B, MPa−4 | 0 | 0.00000200 |
C, MPa−3 | 0.00000551 | −0.00000243 |
D, MPa−2 | 0.00009256 | 0.00012034 |
E, MPa−1 | −0.00133489 | −0.01709066 |
F | 0.99979310 | 1.00027004 |
R² | 0.98691955 | 0.99889577 |
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Michler, T.; Elsässer, C.; Wackermann, K.; Schweizer, F. Effect of Hydrogen in Mixed Gases on the Mechanical Properties of Steels—Theoretical Background and Review of Test Results. Metals 2021, 11, 1847. https://doi.org/10.3390/met11111847
Michler T, Elsässer C, Wackermann K, Schweizer F. Effect of Hydrogen in Mixed Gases on the Mechanical Properties of Steels—Theoretical Background and Review of Test Results. Metals. 2021; 11(11):1847. https://doi.org/10.3390/met11111847
Chicago/Turabian StyleMichler, Thorsten, Christian Elsässer, Ken Wackermann, and Frank Schweizer. 2021. "Effect of Hydrogen in Mixed Gases on the Mechanical Properties of Steels—Theoretical Background and Review of Test Results" Metals 11, no. 11: 1847. https://doi.org/10.3390/met11111847