REE Incorporation into Calcite Individual Crystals as One Time Spike Addition
Abstract
:1. Introduction
2. Materials and Methods
2.1. Calcite Precipitation
2.2. Analyses of Fluids
2.3. Analyses of Solids
3. Results
4. Discussion
4.1. Calculating of Partition Coefficinets
4.2. Comparison of REE Partitioning Values between Three Experiments
4.3. Comparison with Other Studies
5. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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t | REE | pH | Volume (spike) | REE (spike) | Volume (gr.med.) | REE * (gr.med.) | REE (gr.med.) | Ca# (gr.med.) |
---|---|---|---|---|---|---|---|---|
days | mL | ppm | mL | ppm | mol/kg H2O | mol/kg H2O | ||
DC-1, 24.6 °C | ||||||||
0 | Sm | 8.01 | 1 | 0.2 | 1940 | 1.03 × 10−4 | 6.86 × 10−10 | 5.90 × 10−3 |
24 | La | 8.02 | 1 | 0.2 | 1895 | 1.06 × 10−4 | 7.60 × 10−10 | 5.11 × 10−3 |
36 | Nd | 8.05 | 1 | 0.2 | 1721 | 1.16 × 10−4 | 8.06 × 10−10 | 4.76 × 10−3 |
86 | Tb | 8.15 | 1 | 0.5 | 1514 | 3.30 × 10−4 | 2.08 × 10−9 | 3.52 × 10−3 |
DC-2, 2 °C | ||||||||
32 | La | 8.76 | 1 | 0.2 | 465 | 4.30 × 10−4 | 3.10 × 10−9 | n/a |
63 | Nd | 8.74 | 1 | 0.2 | 455 | 4.40 × 10−4 | 3.05 × 10−9 | n/a |
DC-3, 21.7 °C | ||||||||
0 | Sm | 7.83 | 1 | 0.2 | 840 | 2.38 × 10−4 | 1.58 × 10−9 | 2.09 × 10−3 |
1.2 | La | 7.70 | 1 | 0.2 | 820 | 2.44 × 10−4 | 1.76 × 10−9 | 1.90 × 10−3 |
REE | (REE/Ca)fluid | (REE/Ca)calcite | KREE | DREE |
---|---|---|---|---|
DC-1, 24.6 °C (2 crystals) | ||||
Sm | 1.16 × 10−4 | (0.93–4.1) × 10−3 | 8.0.2–35.34 | 13,418–59,153 |
La | 1.49 × 10−4 | (1.4–3.2) × 10−3 | 10.74–21.48 | 20,867–41,734 |
Nd | 1.69 × 10−4 | (1.5–2.2) × 10−3 | 8.88–13.02 | 18,446–27,055 |
Tb | 5.90 × 10−4 | (1.4–4.1) × 10−3 | 2.03–3.81 | 6671–19,538 |
DC-2, 2 °C (2 crystals) | ||||
La | n/a | (5.32–5.51) × 10−3 | n/a | 17,010–17,617 |
Nd | n/a | (4.38–5.79) × 10−3 | n/a | 14,234–18,816 |
DC-3, 21.7 °C (3 crystals) | ||||
Sm | 7.57 × 10−4 | (5.82–5.90) × 10−4 | 0.769–0.0779 | 8241–8354 |
La | 9.22 × 10−4 | 6.58 × 10−4 | 0.714 | 2104 |
Gr.med. | Ca, mol/kg | REE, mol/kg | pH | pCO2 | Ω | T °C | KREE | Study |
---|---|---|---|---|---|---|---|---|
0.5 M NH4Cl | (2.7–5.9) × 10−3 | (6.8–8.1) × 10−10 | 8.01–8.05 | n/a | 1.8 ± 0.29 | 24.6 | 8.02–35.34 | 1 |
0.11 M NaCl | 8.73 × 10−3 | (0.6–3) × 10−10 | 7.5–8.5 | n/a | n/a | 21–26 | 3.5–10 | 2 |
ASW | 1.06 × 10−2 | (0.0001–1) × 10−7 | 7.4–7.8 | 0.0031 | 3.5–15 | 25 | 1585–2512 | 3 |
0.27 M NaCl | 2.25 × 10−3 | (1.8–2.0) × 10−11 | 8.4–8.5 | n/a | n/a | 25 | 86–94 | 4 |
0.1 M NaCl | 2.08 × 10−2 | (0.01–1) × 10−7 | 6.0 | 0.91 | 1–5 | 25 | 100–1000 | 5 |
0.1 M NaClO4 | 1.00 × 10−2 | (0.1–7) × 10−9 | 6.0 | 1 | 1 | 25 | 477–1575 | 6 |
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Gabitov, R.I.; Sadekov, A.; Migdisov, A. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition. Minerals 2017, 7, 204. https://doi.org/10.3390/min7110204
Gabitov RI, Sadekov A, Migdisov A. REE Incorporation into Calcite Individual Crystals as One Time Spike Addition. Minerals. 2017; 7(11):204. https://doi.org/10.3390/min7110204
Chicago/Turabian StyleGabitov, Rinat I., Aleksey Sadekov, and Artas Migdisov. 2017. "REE Incorporation into Calcite Individual Crystals as One Time Spike Addition" Minerals 7, no. 11: 204. https://doi.org/10.3390/min7110204