Polymer Nanocomposites via Click Chemistry Reactions
Abstract
:1. Introduction
2. Click Chemistry-Based Methodologies in Polymer Nanocomposite Fabrication
2.1. Polymer Nanocomposites via CuAAC and Metal-Free Click Reactions
2.2. Polymer Nanocomposites via Diels–Alder Reactions
2.3. Polymer Nanocomposites via Thiol-X Reactions
3. General Overview and Future Perspectives
4. Conclusions
Author Contributions
Conflicts of Interest
References
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Click Reaction | Advantages | Limitations | Comments |
---|---|---|---|
CuAAC click reaction | High selectivity, rapid and quantitative transformations, tolerance to diverse organic solvents and water, stability, orthogonality. | Need to use (toxic) metal catalyst. Removal of the catalyst. | Particularly suitable for effective coupling of nanofillers and matrices. Provides improvement in interfacial compatibility. |
Metal-free click reaction | Selectivity, high reactivity, biocompatibility and stability. | Substrates such as strained cyclooctynes are not so common and expensive materials. | Suitable if toxic metal catalyst is an issue, especially in biomedical applications. |
Diels–Alder reaction | Activation through heating (could be beneficial in certain cases). Most of the time no byproduct formation. Reversibility of the reaction. | Heating requirement (could be a problem in certain cases), relatively prolonged reactions times. | Nanofiller surface can act as a substrate which resolves the destructive surface chemical treatments. Reversible nature is useful in self-healing materials. |
Thiol-ene and thiol-yne reactions | High efficiency, high conversions, UV or heat-triggered activation. | Thiols are prone to many side reactions and have low self-stability. Especially the volatile thiols have disagreeable odors. | Reaction mechanism may induce more homogeneous network formation and reduces the network shrinkage. UV-triggered nature might be useful in coating applications. |
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Arslan, M.; Tasdelen, M.A. Polymer Nanocomposites via Click Chemistry Reactions. Polymers 2017, 9, 499. https://doi.org/10.3390/polym9100499
Arslan M, Tasdelen MA. Polymer Nanocomposites via Click Chemistry Reactions. Polymers. 2017; 9(10):499. https://doi.org/10.3390/polym9100499
Chicago/Turabian StyleArslan, Mehmet, and Mehmet Atilla Tasdelen. 2017. "Polymer Nanocomposites via Click Chemistry Reactions" Polymers 9, no. 10: 499. https://doi.org/10.3390/polym9100499