Polyelectrolyte Threading through a Nanopore
AbstractThreading charged polymers through a nanopore, driven by electric fields E, is investigated by means of Langevin dynamics simulations. The mean translocation time 〈 τ 〉 is shown to follow a scaling law Nα, and the exponent α increases monotonically from 1.16 (4) to 1.40 (3) with E. The result is double-checked by the calculation of mean square displacement of translocation coordinate, which asserts a scaling behavior tβ (for t near τ) with β complying with the relation αβ = 2. At a fixed chain length N, 〈τ〉 displayed a reciprocal scaling behavior E−1 in the weak and also in the strong fields, connected by a transition E−1.64(5) in the intermediate fields. The variations of the radius of gyration of chain and the positions of chain end are monitored during a translocation process; far-from-equilibrium behaviors are observed when the driving field is strong. A strong field can strip off the condensed ions on the chain when it passes the pore. The total charges of condensed ions are hence decreased. The studies for the probability and density distributions reveal that the monomers in the trans-region are gathered near the wall and form a pancake-like density profile with a hump cloud over it in the strong fields, due to fast translocation. View Full-Text
- Supplementary File 1:
Supplementary (PDF, 5335 KB)
Scifeed alert for new publicationsNever miss any articles matching your research from any publisher
- Get alerts for new papers matching your research
- Find out the new papers from selected authors
- Updated daily for 49'000+ journals and 6000+ publishers
- Define your Scifeed now
Hsiao, P.-Y. Polyelectrolyte Threading through a Nanopore. Polymers 2016, 8, 73.
Hsiao P-Y. Polyelectrolyte Threading through a Nanopore. Polymers. 2016; 8(3):73.Chicago/Turabian Style
Hsiao, Pai-Yi. 2016. "Polyelectrolyte Threading through a Nanopore." Polymers 8, no. 3: 73.
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.