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Polymers 2016, 8(1), 5; doi:10.3390/polym8010005

Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides

1
Instituto de Ciencia Molecular, Universidad de Valencia, Catedrático José Beltrán 2, Paterna, Valencia 46980, Spain
2
Department of Chemistry and Pharmacy and Institute of Advanced Materials and Processes (ZMP), University Erlangen-Nuremberg, Henkestr. 42, Erlangen 91054 and Dr.-Mack Str. 81, Fürth 90762, Germany
3
Departamento de Química Inorgánica and Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid, Madrid 28049, Spain
4
Instituto de Catálisis y Petroleoquímica, Cantoblanco, Madrid 28049, Spain
5
Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia), Cantoblanco, Madrid 28049, Spain
*
Authors to whom correspondence should be addressed.
Academic Editor: Hsing-Lin Wang
Received: 16 September 2015 / Revised: 18 December 2015 / Accepted: 24 December 2015 / Published: 29 December 2015
(This article belongs to the Special Issue Coordination Polymers: New Materials for Multiple Applications)
View Full-Text   |   Download PDF [5122 KB, uploaded 29 December 2015]   |  

Abstract

The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora of different functional hybrid systems. View Full-Text
Keywords: hybrid materials; layered double hydroxides; coordination polymers; magnetic properties; layered compounds hybrid materials; layered double hydroxides; coordination polymers; magnetic properties; layered compounds
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Abellán, G.; Amo-Ochoa, P.; Fierro, J.L.G.; Ribera, A.; Coronado, E.; Zamora, F. Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides. Polymers 2016, 8, 5.

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