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Polymers 2011, 3(1), 1-9; doi:10.3390/polym3010001

Synthesis of Polypyrrole-Intercalated Grafted Zirconium Phosphate Films by Anodic Electrodeposition and Their Electrochemical Capacities

Center for Crystal Science and Technology, University of Yamanashi, 7-32 Miyamae, Kofu, Yamanashi 400-8511, Japan
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Received: 4 November 2010 / Revised: 30 November 2010 / Accepted: 20 December 2010 / Published: 23 December 2010
(This article belongs to the Special Issue Conductive Polymers)
View Full-Text   |   Download PDF [2152 KB, uploaded 24 December 2010]   |  

Abstract

Ternary hybrid film composed of a-zirconium phosphate nanosheet, 1,2-bis(dimethylchlorosilyl)ethane and polypyrrole was prepared by anodic electrodeposition. In the hybrid film, ordered a-zirconium nanosheets with grafts by silylation lay down parallel to the substrate and the polypyrrole molecules were intercalated between the nanosheets. The electrochemical measurements confirmed that the hybrid film indicated capacitive behavior and the redox activity increase by approximately 25%. View Full-Text
Keywords: electrodeposition; electrochemical capacitor; graft; polypyrrole; zirconium phosphate electrodeposition; electrochemical capacitor; graft; polypyrrole; zirconium phosphate
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Takei, T.; Dong, Q.; Yonesaki, Y.; Kumada, N.; Kinomura, N. Synthesis of Polypyrrole-Intercalated Grafted Zirconium Phosphate Films by Anodic Electrodeposition and Their Electrochemical Capacities. Polymers 2011, 3, 1-9.

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