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Crystals 2017, 7(3), 91; doi:10.3390/cryst7030091

Growth and Physical Properties of SrxCa1−xCrO3 Single Crystals

1,2
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1,3,4
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1,3,4
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1,3,4
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1,3,4
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1,3,4
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2,5,* and 1,3,4,*
1
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
2
Department of Physics, University of Science and Technology Beijing, Beijing 100083, China
3
School of Physics, University of Chinese Academy of Sciences, Beijing 100190, China
4
Collaborative Innovation Center of Quantum Matter, Beijing 100190, China
5
College of Science, China Three Gorges University, Yichang 443002, China
*
Authors to whom correspondence should be addressed.
Academic Editors: Alain Largeteau and Mythili Prakasam
Received: 30 November 2016 / Revised: 7 March 2017 / Accepted: 13 March 2017 / Published: 21 March 2017
(This article belongs to the Special Issue Crystal Growth for Optoelectronic and Piezoelectric Applications)
View Full-Text   |   Download PDF [16878 KB, uploaded 22 March 2017]   |  

Abstract

Perovskites SrxCa1−xCrO3 attract much attention due to the controversy on the anomalous electronic state. In this study, we synthesized a series of SrxCa1−xCrO3 (0 ≤ x ≤ 1) single crystals under high pressure and high temperature conditions with self-oxidization. The crystal structure was determined using X-ray diffraction (XRD). With the increase of x, the structure transformed from orthorhombic to tetragonal to cubic. Antiferromagnetism was observed except for SrCrO3, and the TN decreased with increased x. All samples demonstrated semiconductive behavior by electrical resistivity measurement. View Full-Text
Keywords: high pressure; self-oxidization; single crystal; magnetic properties high pressure; self-oxidization; single crystal; magnetic properties
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Cao, L.; Jin, A.; Gu, C.; Bai, H.; Long, Y.; Yu, R.; Pan, L.; Jin, C. Growth and Physical Properties of SrxCa1−xCrO3 Single Crystals. Crystals 2017, 7, 91.

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