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Crystals 2017, 7(10), 297; doi:10.3390/cryst7100297

Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture

College of Chemistry & Chemical Engineering, Fuyang Normal University, Fuyang 236041, China
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Academic Editor: Helmut Cölfen
Received: 23 July 2017 / Revised: 24 September 2017 / Accepted: 29 September 2017 / Published: 2 October 2017
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Abstract

A new complex, [Cu4(HL)4(H2O)14] (1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride), has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and powder X-ray diffraction (PXRD). The result of the X-ray diffraction analysis reveals that the complex crystallizes in monoclinic, space group C2/c and three unique Cu(II) atoms that are connected by partially deprotonated HL2− anion to form a cyclic structure. The rich hydrogen bonding and π-π non-covalent packing interactions extend cyclic units into a three-dimensional (3D) supramolecular polymer. Moreover, the thermogravimetric (TG) analysis and water vapor adsorption property of 1 were also discussed. View Full-Text
Keywords: Cu(II) complex; supramolecular architecture; water vapor adsorption Cu(II) complex; supramolecular architecture; water vapor adsorption
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Qiao, R.; Zhang, Z.-Y.; Zhu, M.-A. Synthesis, Crystal Structure and Water Vapor Adsorption Properties of a Porous Supramolecular Architecture. Crystals 2017, 7, 297.

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