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Crystals 2017, 7(1), 3; doi:10.3390/cryst7010003

Synthesis, Crystal Structure of a Novel Mn Complex with Nicotinoyl-Glycine

1,2
,
1,* and 1
1
Department of Chemistry, Qinghai Normal University, Xining 810008, China
2
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China
*
Author to whom correspondence should be addressed.
Academic Editor: Helmut Cölfen
Received: 9 November 2016 / Revised: 21 December 2016 / Accepted: 23 December 2016 / Published: 30 December 2016
View Full-Text   |   Download PDF [2150 KB, uploaded 30 December 2016]   |  

Abstract

A novel manganese complex, C16H26MnN4O12, was synthesized by the reaction of nicotinoyl-glycine and NaOH in an ethanol/water solution and structurally characterized by elemental analysis, UV-vis spectrum, IR spectrum and single-crystal X-ray diffraction analysis. The crystal of the complex belongs to the triclinic space group P1 with a = 7.8192(16) Å, b = 8.8800(18) Å, c = 9.0142(18) Å, α = 83.14(3)°, β = 65.27(3)°, γ = 81.67(3)°, V = 516.3(2) Å3, Z = 1, Dx = 1.542 mg·m−3, μ = 0.66 mm−1, F(000) = 271, and final R1 = 0.0381, ωR2 = 0.0964. The nicotinoyl-glycine ligand acts as a bridging ligand to connect the manganese ions by the hydrogen interactions; thus, the complex expands into a 3D supramolecular net structure. View Full-Text
Keywords: nicotinoyl-glycine; manganese complex; synthesis; crystal structure nicotinoyl-glycine; manganese complex; synthesis; crystal structure
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Wang, X.; Chen, B.; He, M. Synthesis, Crystal Structure of a Novel Mn Complex with Nicotinoyl-Glycine. Crystals 2017, 7, 3.

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