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Inorganic Amino-Nitro-Guanidinium Derivatives
Abstract1-Amino-3-nitroguanidine (ANQ, 1) was synthesized by hydrazinolysis of nitroguanidine (NQ) with hydrazine hydrate. Four different amino-nitroguanidinium salts (chloride (2), bromide (3), iodide (4) and sulfate (5)) were synthesized and structurally characterized by low-temperature X-ray diffraction. The halides 2–4 could only be obtained crystalline as monohydrates. In addition, they were characterized by NMR and vibrational spectroscopy, elemental analysis and the sensitivities towards impact, friction and electrostatic discharge were determined. The compounds can be used in silver (AgX, X = Cl, Br, I) and barium (BaSO4) based metathesis reactions in order to form more complex salts of 1-amino-nitroguanidine.
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Fischer, N.; Klapötke, T.M.; Lux, K.; Martin, F.A.; Stierstorfer, J. Inorganic Amino-Nitro-Guanidinium Derivatives. Crystals 2012, 2, 675-689.View more citation formats
Fischer N, Klapötke TM, Lux K, Martin FA, Stierstorfer J. Inorganic Amino-Nitro-Guanidinium Derivatives. Crystals. 2012; 2(2):675-689.Chicago/Turabian Style
Fischer, Niko; Klapötke, Thomas M.; Lux, Karin; Martin, Franz A.; Stierstorfer, Jörg. 2012. "Inorganic Amino-Nitro-Guanidinium Derivatives." Crystals 2, no. 2: 675-689.