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Catalysts 2017, 7(10), 284; doi:10.3390/catal7100284

Synthesis of Stereodiblock Polybutadiene Using Cp*Nd(BH4)2(thf)2 as a Catalyst

Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-hiroshima 739-8527, Japan
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Received: 7 September 2017 / Revised: 18 September 2017 / Accepted: 19 September 2017 / Published: 25 September 2017
(This article belongs to the Special Issue Catalysts for the Controlled Polymerization of Conjugated Dienes)
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Abstract

Butadiene polymerization, in both a highly cis- and trans-specific manner, was achieved by using a Cp*Nd(BH4)2(thf)2–Bu2Mg system as an initiator. The cis-/trans- ratio can be tuned by the amount of trialkylaluminum-depleted modified methylaluminoxane (dMMAO). The cis-regularity of the polymer was much higher than those obtained by Nd(BH4)3(thf)3. The molecular weight of cis-regular polymer was increased according to polymer yield, showing that there was no termination or chain transfer reaction during the polymerization. Synthesis of stereodiblock polybutadiene, which showed a high melting temperature (Tm) compared with stereodiblock polyisoprene, was also performed by the addition dMMAO during the polymerization. View Full-Text
Keywords: coordination polymerization; neodymium catalyst; polyconjugated dienes; stereoblock polymer; rubber coordination polymerization; neodymium catalyst; polyconjugated dienes; stereoblock polymer; rubber
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Tanaka, R.; Shinto, Y.; Nakayama, Y.; Shiono, T. Synthesis of Stereodiblock Polybutadiene Using Cp*Nd(BH4)2(thf)2 as a Catalyst. Catalysts 2017, 7, 284.

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