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Catalysts 2016, 6(7), 97; doi:10.3390/catal6070097

Bimetallic Catalysts Containing Gold and Palladium for Environmentally Important Reactions

1
Materials Science Research Institute (MSRI), King Abdulaziz City for Science and Technology (KACST), P. O. Box 6086, Riyadh 11442, Saudi Arabia
2
Department of Heterogeneous Catalytic Processes, Leibniz Institute for Catalysis, Albert-Einstein-Str. 29a, Rostock 18059, Germany
*
Authors to whom correspondence should be addressed.
Academic Editor: John R. (JR) Regalbuto
Received: 11 April 2016 / Revised: 8 June 2016 / Accepted: 24 June 2016 / Published: 5 July 2016
(This article belongs to the Special Issue Rational Synthesis of Supported Bimetallic Catalysts)
View Full-Text   |   Download PDF [4897 KB, uploaded 5 July 2016]   |  

Abstract

Supported bimetallic nanoparticles (SBN) are extensively used as efficient redox catalysts. This kind of catalysis particularly using SBN has attracted immense research interest compared to their parent metals due to their unique physico-chemical properties. The primary objective of this contribution is to provide comprehensive overview about SBN and their application as promising catalysts. The present review contains four sections in total. Section 1 starts with a general introduction, recent progress, and brief summary of the application of SBN as promising catalysts for different applications. Section 2 reviews the preparation and characterization methods of SBN for a wide range of catalytic reactions. Section 3 concentrates on our own results related to the application of SBN in heterogeneous catalysis. In this section, the oxidation of cyclohexane to adipic acid (an eco-friendly and novel approach) will be discussed. In addition, the application of bimetallic Pd catalysts for vapor phase toluene acetoxylation in a fixed bed reactor will also be highlighted. Acetoxylation of toluene to benzyl acetate is another green route to synthesize benzyl acetate in one step. Finally, Section 4 describes the summary of the main points and also presents an outlook on the application of SBN as promising catalysts for the production of valuable products. View Full-Text
Keywords: bimetallic catalysts; Pd-Sb catalysts; Au-Ag catalysts; acetoxylation; oxidation bimetallic catalysts; Pd-Sb catalysts; Au-Ag catalysts; acetoxylation; oxidation
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Alshammari, A.; Kalevaru, V.N.; Martin, A. Bimetallic Catalysts Containing Gold and Palladium for Environmentally Important Reactions. Catalysts 2016, 6, 97.

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