Dolomite-Derived Ni-Based Catalysts with Fe Modification for Hydrogen Production via Auto-Thermal Reforming of Acetic Acid
Abstract
:1. Introduction
2. Results
2.1. Auto-Thermal Reforming of Acetic Acid
2.2. Characterizations
2.2.1. Precursors of Catalysts
2.2.2. Oxides of Catalysts
2.2.3. Reduced Catalysts
2.2.4. Spent Catalysts
3. Discussion
4. Materials and Methods
4.1. Catalyst Preparation
4.2. Catalytic Performance Test
4.3. Catalyst Characterization
5. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Catalysts | Nominal Molar Composition | Weight Compositions Analyzed by ICP-AES/% | Surface Area/(m2/g) | Average Pore Size/nm | |||
---|---|---|---|---|---|---|---|
MgO | NiO | CaO | Fe2O3 | ||||
MNC0.8F0.0 | MgNi0.2Ca0.8O2±δ | 39.12 | 15.11 | 45.77 | 0.00 | 4.27 | 7.44 |
MNC0.7F0.1 | MgNi0.2Ca0.7Fe0.1O2±δ | 38.42 | 14.40 | 39.67 | 7.51 | 6.62 | 6.52 |
MNC0.5F0.3 | MgNi0.2Ca0.5Fe0.3O2±δ | 37.74 | 13.91 | 26.33 | 22.02 | 8.71 | 6.16 |
MNC0.3F0.5 | MgNi0.2Ca0.3Fe0.5O2±δ | 34.84 | 13.29 | 16.68 | 35.19 | 11.53 | 5.87 |
MNC0.0F0.8 | MgNi0.2Fe0.8O2±δ | 33.01 | 12.31 | 0.00 | 54.68 | 4.69 | 5.37 |
Catalysts | ||||||
---|---|---|---|---|---|---|
MNC0.8F0.0 | 98.2 | 67.4 | 18.9 | 3.3 | 10.4 | 2.09 |
MNC0.7F0.1 | 99.0 | 59.1 | 30.9 | 4.0 | 5.9 | 2.31 |
MNC0.5F0.3 | 99.9 | 61.1 | 32.3 | 3.7 | 2.9 | 2.59 |
MNC0.3F0.5 | 99.9 | 64.6 | 25.8 | 3.7 | 5.9 | 2.43 |
MNC0.0F0.8 | 100.0 | 69.1 | 16.7 | 3.2 | 11.0 | 2.07 |
Species | MNC0.8F0.0 | MNC0.5F0.3 | MNC0.0F0.8 | |||
---|---|---|---|---|---|---|
Reduced | Spent | Reduced | Spent | Reduced | Spent | |
Ni0/(Ni0v+ Ni2+)/% | 9.0 | 3.7 | 12.5 | 8.8 | 14.1 | 6.7 |
Fe0/(Fe0 + Fe2+ + Fe3+)/% | N.A. | N.A. | 70.9 | 12.9 | 77.6 | 4.6 |
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Zhong, X.; Xie, W.; Wang, N.; Duan, Y.; Shang, R.; Huang, L. Dolomite-Derived Ni-Based Catalysts with Fe Modification for Hydrogen Production via Auto-Thermal Reforming of Acetic Acid. Catalysts 2016, 6, 85. https://doi.org/10.3390/catal6060085
Zhong X, Xie W, Wang N, Duan Y, Shang R, Huang L. Dolomite-Derived Ni-Based Catalysts with Fe Modification for Hydrogen Production via Auto-Thermal Reforming of Acetic Acid. Catalysts. 2016; 6(6):85. https://doi.org/10.3390/catal6060085
Chicago/Turabian StyleZhong, Xinyan, Wei Xie, Ning Wang, Yiping Duan, Ruishu Shang, and Lihong Huang. 2016. "Dolomite-Derived Ni-Based Catalysts with Fe Modification for Hydrogen Production via Auto-Thermal Reforming of Acetic Acid" Catalysts 6, no. 6: 85. https://doi.org/10.3390/catal6060085