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Catalysts 2016, 6(4), 50; doi:10.3390/catal6040050

New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review

1
Department of Kinetics and Catalysis, Semenov Institute of Chemical Physics, Russian Academy of Sciences, ulitsa Kosygina, dom 4, Moscow 119991, Russia
2
Chair of Chemistry and Physics, Plekhanov Russian University of Economics, Stremyannyi pereulok, dom 36, Moscow 117997, Russia
Academic Editor: Keith Hohn
Received: 31 January 2016 / Revised: 13 March 2016 / Accepted: 16 March 2016 / Published: 24 March 2016
(This article belongs to the Special Issue Catalytic Functionalization of C‒H Bonds)

Abstract

This review describes new reactions catalyzed by recently discovered types of metal complexes and catalytic systems (catalyst + co-catalyst). Works of recent years (mainly 2010–2016) devoted to the oxygenations of saturated, aromatic hydrocarbons and other carbon–hydrogen compounds are surveyed. Both soluble metal complexes and solid metal compounds catalyze such transformations. Molecular oxygen, hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants. View Full-Text
Keywords: alkanes; alcohols; alkyl hydroperoxides; aromatics; hydrogen peroxide; mechanisms of oxidation; metal-complex catalysis; oxygen; oxygenation; peroxyacids alkanes; alcohols; alkyl hydroperoxides; aromatics; hydrogen peroxide; mechanisms of oxidation; metal-complex catalysis; oxygen; oxygenation; peroxyacids
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Shul’pin, G.B. New Trends in Oxidative Functionalization of Carbon–Hydrogen Bonds: A Review. Catalysts 2016, 6, 50.

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