Catalysts 2012, 2(4), 412-421; doi:10.3390/catal2040412
Communication

Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium

, , , ,  and * email
Received: 14 June 2012; in revised form: 27 August 2012 / Accepted: 5 September 2012 / Published: 11 October 2012
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The complex [(κ3-(N,N,O-py2B(Me)OH)Ru(NCMe)3]+ TfO (1) is a catalyst for transfer dehydrogenation of alcohols, which was designed to function through a cooperative transition state in which reactivity was split between boron and ruthenium. We show here both stoichiometric and catalytic evidence to support that in the case of alcohol oxidation, the mechanism most likely involves reactivity only at the ruthenium center.
Keywords: bifunctional catalyst; oxidation; hydride abstraction; mechanism
PDF Full-text Download PDF Full-Text [431 KB, uploaded 11 October 2012 13:45 CEST]

Export to BibTeX |
EndNote


MDPI and ACS Style

Lu, Z.; Malinoski, B.; Flores, A.V.; Conley, B.L.; Guess, D.; Williams, T.J. Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium. Catalysts 2012, 2, 412-421.

AMA Style

Lu Z, Malinoski B, Flores AV, Conley BL, Guess D, Williams TJ. Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium. Catalysts. 2012; 2(4):412-421.

Chicago/Turabian Style

Lu, Zhiyao; Malinoski, Brock; Flores, Ana V.; Conley, Brian L.; Guess, Denver; Williams, Travis J. 2012. "Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium." Catalysts 2, no. 4: 412-421.

Catalysts EISSN 2073-4344 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert