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Catalysts 2012, 2(4), 412-421; doi:10.3390/catal2040412

Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium

, , , ,  and *
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA
* Author to whom correspondence should be addressed.
Received: 14 June 2012 / Revised: 27 August 2012 / Accepted: 5 September 2012 / Published: 11 October 2012
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The complex [(κ3-(N,N,O-py2B(Me)OH)Ru(NCMe)3]+ TfO (1) is a catalyst for transfer dehydrogenation of alcohols, which was designed to function through a cooperative transition state in which reactivity was split between boron and ruthenium. We show here both stoichiometric and catalytic evidence to support that in the case of alcohol oxidation, the mechanism most likely involves reactivity only at the ruthenium center.
Keywords: bifunctional catalyst; oxidation; hydride abstraction; mechanism bifunctional catalyst; oxidation; hydride abstraction; mechanism
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Lu, Z.; Malinoski, B.; Flores, A.V.; Conley, B.L.; Guess, D.; Williams, T.J. Alcohol Dehydrogenation with a Dual Site Ruthenium, Boron Catalyst Occurs at Ruthenium. Catalysts 2012, 2, 412-421.

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