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Catalysts 2012, 2(1), 101-120; doi:10.3390/catal2010101
Review
Monometallic Supported Gold Catalysts in Organic Transformations: Ring Making and Ring Breaking
1
Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged H-6720, Hungary
2
Department of Inorganic and Analytical Chemistry, University of Szeged, Dóm tér 7, Szeged H-6720, Hungary
* Author to whom correspondence should be addressed.
Received: 10 October 2011; in revised form: 19 December 2011 / Accepted: 9 January 2012 / Published: 1 February 2012
(This article belongs to the Special Issue Gold Catalysts)
Abstract: Supported gold catalysts are highly active in oxidation reactions. Beside the most frequently studied CO oxidation, they are readily applied in the epoxidation of more or less complex olefinic compounds using air or oxygen directly or other oxidants like peroxides of various kinds. Less frequently though, the reverse reaction, ring opening with single or double C–O scission is also investigated. These and other ring making and breaking reactions are reviewed, and the catalytic roles of gold species are described.
Keywords: supported gold catalysts; oxygen-containing rings; ring synthesis; ring transformations
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MDPI and ACS Style
Csankó, K.; Sipos, P.; Pálinkó, I. Monometallic Supported Gold Catalysts in Organic Transformations: Ring Making and Ring Breaking. Catalysts 2012, 2, 101-120.
AMA StyleCsankó K, Sipos P, Pálinkó I. Monometallic Supported Gold Catalysts in Organic Transformations: Ring Making and Ring Breaking. Catalysts. 2012; 2(1):101-120.
Chicago/Turabian StyleCsankó, Krisztián; Sipos, Pál; Pálinkó, István. 2012. "Monometallic Supported Gold Catalysts in Organic Transformations: Ring Making and Ring Breaking." Catalysts 2, no. 1: 101-120.
Catalysts
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