Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReOx-Pd/CeO2 Catalyst
Abstract
:1. Introduction
2. Results and Discussion
2.1. Catalyst Characterization
2.1.1. XRF
2.1.2. ICP-OES
2.1.3. SEM
2.1.4. TPR
2.1.5. In-Situ Raman
2.2. Reaction Order Determination
2.3. Activation Energy Determination
2.4. Mass Transfer Evaluations
2.4.1. Weisz–Prater Criterion
2.4.2. External Mass Transfer
2.4.3. Xylitol Concentration Effects
3. Experimental
3.1. Chemicals
3.2. Catalyst Preparation
3.3. Catalyst Characterization
3.3.1. XRF
3.3.2. ICP-OES
3.3.3. SEM
3.3.4. XRD
3.3.5. TPR
3.3.6. In-Situ Raman
3.4. Reactor Setup
3.5. Kinetic Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
Abbreviations
References
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Reaction/Catalyst | Activation Energy | Method | Reference |
---|---|---|---|
DODH of 1,4-anhydroerythritol over ReO2/CeO2 | 153 kJ/mol | DFT | Ota et al., 2016 [11] |
DODH of 1,4-anhydroerythritol over ReO/CeO2 | 109 kJ/mol | DFT | Xi et al., 2018 [15] |
DODH of 1,4-anhydroerythritol over ReO-Pd/CeO2 | 111 kJ/mol | DFT | Xi et al., 2018 [15] |
DODH of 1,4-anhydroerythritol over ReO2(2O)/TiO2(101) | 71.4 kJ/mol | DFT | Xi et al., 2020 [18] |
DODH 1,4-anhydroerythritol over MoO2(2O)/TiO2(101) | 160.2 kJ/mol | DFT | Xi et al., 2020 [18] |
DODH of 3-Butene-1,2-diol over CH3ReO2 | 118.8 kJ/mol | DFT | Wu et al., 2016 [16] |
DODH of 3-Butene-1,2-diol over CH3ReO(OH)2 | 79.9 kJ/mol | DFT | Wu et al., 2016 [16] |
DODH of methyl α-l-rhamnopyranoside over ReOx-Pd/CeO2 | 65, 63 kJ/mol | DFT, Arrhenius | Cao et al., 2020 [17] |
DODH of methyl α-l-fucopyranoside over ReOx-Pd/CeO2 | 77, 73 kJ/mol | DFT, Arrhenius | Cao et al., 2020 [17] |
Kinetic Parameter | Value | 95% CI |
---|---|---|
A | 44 mol s−1 gcat−1 | (23, 65) |
B | −3.79 × 105 J mol−1 | (−5.76 × 105, −2.34 × 10−5) |
C | 6.03 × 108 J2 mol−2 | (3.52 × 108, 8.53 × 108) |
Temperature (K) | Activation Energy (kJ/mol) |
---|---|
393.15 | 10.2 |
403.15 | 19.4 |
413.15 | 28.1 |
418.15 | 32.3 |
423.15 | 36.4 |
428.15 | 40.4 |
433.15 | 44.3 |
438.15 | 48.1 |
443.15 | 51.8 |
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MacQueen, B.; Royko, M.; Crandall, B.S.; Heyden, A.; Pagán-Torres, Y.J.; Lauterbach, J. Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReOx-Pd/CeO2 Catalyst. Catalysts 2021, 11, 108. https://doi.org/10.3390/catal11010108
MacQueen B, Royko M, Crandall BS, Heyden A, Pagán-Torres YJ, Lauterbach J. Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReOx-Pd/CeO2 Catalyst. Catalysts. 2021; 11(1):108. https://doi.org/10.3390/catal11010108
Chicago/Turabian StyleMacQueen, Blake, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, and Jochen Lauterbach. 2021. "Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReOx-Pd/CeO2 Catalyst" Catalysts 11, no. 1: 108. https://doi.org/10.3390/catal11010108