Fine Characterization of Natural SiO2-Doped Catalyst Derived from Mussel Shell with Potential Photocatalytic Performance for Organic Dyes
Abstract
:1. Introduction
2. Results
2.1. Morphology Analysis
2.2. Chemical Composition Analysis
2.3. Optical Absorption Tests
2.4. Photocatalytic Performance
2.5. Active Species Detection
2.6. Total Organic Carbon (TOC)Analysis of Degradation Products
2.7. Photocatalytic Degradation Products Analysis
3. Materials and Methods
3.1. Initial Materials
3.2. Mussel Shell Photocatalyst Preparation
3.3. Characterization
3.4. Photodegradation of Organic Dyes
3.5. Active Species Detection
3.6. Analysis of the Degradation Products
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Metal Element | Ca | Al | Si | Fe | K | Mg | Ti | Zr | Mn |
---|---|---|---|---|---|---|---|---|---|
HAS | 1621.5 | 33,437.8 | 233,580.0 | 27,243.6 | 7512.8 | 22,660.6 | 3622.1 | 779.7 | 127.4 |
OS | 385,000.0 | 125.4 | 642.0 | 10.4 | 44.9 | 967.0 | - | - | 2.8 |
Catalyst | Dye | Dye (mL) | Dye Conc. (mg/L) | Catalyst Content (g) | Reaction Time (min) | K (min−1) | Degradation Rate (%) | Ref. |
---|---|---|---|---|---|---|---|---|
Bi2MoO6/Graphene | MB | 100 | 0.01 | 0.05 | 120 | 0.014 | 80 | [42] |
TiO2@SiO2 | MO | 15 | 20 | 0.02 | 180 | - | 97.5 | [43] |
BKBC | MB | 50 | 80 | 0.01 | 60 | 0.0079 | 61.39 | [23] |
AKB | MB | 50 | 80 | 0.01 | 60 | 0.0073 | 94.12 | [23] |
BiOI | MO | 50 | 10 | 0.05 | 240 | 0.0843 | 31.3 | [44] |
BiOI | RB | 50 | 10 | 0.05 | 240 | 0.0502 | 17.8 | [44] |
HAS | MB | 40 | 60 | 0.02 | 540 | 0.0059 | 99.14 | This study |
HAS | RhB | 40 | 24 | 0.02 | 240 | 0.0040 | 92.59 | This study |
Parameter | Condition |
---|---|
Column | Agilent ZORBAX SB-C18 |
Eluent types | methanol-water (80:20, V/V) |
Flow rate (mL/min) | 0.3 |
Injection Volume (μL) | 5 |
Nebulizer pressure (psi) | 70 |
Column temperature (°C) | 25 |
Capillary voltage (kV) mass range | 3.5 50–700 |
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Wang, Z.; Xia, L.; Chen, J.; Ji, L.; Zhou, Y.; Wang, Y.; Cai, L.; Guo, J.; Song, W. Fine Characterization of Natural SiO2-Doped Catalyst Derived from Mussel Shell with Potential Photocatalytic Performance for Organic Dyes. Catalysts 2020, 10, 1130. https://doi.org/10.3390/catal10101130
Wang Z, Xia L, Chen J, Ji L, Zhou Y, Wang Y, Cai L, Guo J, Song W. Fine Characterization of Natural SiO2-Doped Catalyst Derived from Mussel Shell with Potential Photocatalytic Performance for Organic Dyes. Catalysts. 2020; 10(10):1130. https://doi.org/10.3390/catal10101130
Chicago/Turabian StyleWang, Zhen, Liping Xia, Jinlong Chen, Lili Ji, Yarui Zhou, Yaning Wang, Lu Cai, Jian Guo, and Wendong Song. 2020. "Fine Characterization of Natural SiO2-Doped Catalyst Derived from Mussel Shell with Potential Photocatalytic Performance for Organic Dyes" Catalysts 10, no. 10: 1130. https://doi.org/10.3390/catal10101130