Hydrotalcite-Supported Ag/Pd Bimetallic Nanoclusters Catalyzed Oxidation and One-Pot Aldol Reaction in Water
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis of Catalyst
2.2. Catalytic Performance
3. Materials and Methods
3.1. General Procedure for Oxidation
3.2. General Procedure for Oxidation and One-pot Aldol Reaction in Water
3.2.1. Method A
3.2.2. Method B
3.2.3. Method C
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Entry | Catalyst (Atom%) | Solvent | Base | Temperature (°C) | Yield (%) b |
---|---|---|---|---|---|
1 | Ag-HT (5) | dioxane | Cs2CO3 | 70 | 60 |
2 | Pd-HT (5) | dioxane | Cs2CO3 | 70 | 38 |
3 | Ag/Pd-HT(1:1) (5) | dioxane | Cs2CO3 | 70 | 93 |
4 | Ag/Pd-HT(3:7) (5) | dioxane | Cs2CO3 | 70 | 28 |
5 | Ag/Pd-HT(7:3) (5) | dioxane | Cs2CO3 | 70 | 51 |
6 | Ag/Pd-HT(1:1) (3) | dioxane | Cs2CO3 | 50 | 92 |
7 | Ag/Pd-HT(1:1) (3) | H2O | Cs2CO3 | 50 | 87 |
8 c | Ag/Pd-HT(1:1) (3) | H2O | Cs2CO3 | 50 | 30 |
9 | HT | H2O | Cs2CO3 | 50−70 | ― |
10 | No catalyst | H2O | Cs2CO3 | 50−70 | ― |
11 | Ag/Pd-HT(1:1) (3) | H2O | NaOH | 50 | 90 |
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Karanjit, S.; Tamura, A.; Kashihara, M.; Ushiyama, K.; Shrestha, L.K.; Ariga, K.; Nakayama, A.; Namba, K. Hydrotalcite-Supported Ag/Pd Bimetallic Nanoclusters Catalyzed Oxidation and One-Pot Aldol Reaction in Water. Catalysts 2020, 10, 1120. https://doi.org/10.3390/catal10101120
Karanjit S, Tamura A, Kashihara M, Ushiyama K, Shrestha LK, Ariga K, Nakayama A, Namba K. Hydrotalcite-Supported Ag/Pd Bimetallic Nanoclusters Catalyzed Oxidation and One-Pot Aldol Reaction in Water. Catalysts. 2020; 10(10):1120. https://doi.org/10.3390/catal10101120
Chicago/Turabian StyleKaranjit, Sangita, Ayumu Tamura, Masaya Kashihara, Kazuki Ushiyama, Lok Kumar Shrestha, Katsuhiko Ariga, Atsushi Nakayama, and Kosuke Namba. 2020. "Hydrotalcite-Supported Ag/Pd Bimetallic Nanoclusters Catalyzed Oxidation and One-Pot Aldol Reaction in Water" Catalysts 10, no. 10: 1120. https://doi.org/10.3390/catal10101120