Porous Materials for Hydrolytic Dehydrogenation of Ammonia Borane
Abstract
:1. Introduction
2. Porous Support Materials
2.1. Microporous and Mesoporous Inorganic Support Materials
2.2. Polymer Gels for Support or Immobilization of Active Species
2.3. Metal-Organic Frameworks for Immobilization of Active Species
Catalysts | Active Species | Particle Size (nm) | TOF (mol-H2 min−1 mol-Active Species−1) | Ref. |
---|---|---|---|---|
Co–B/SBA-15 | Co–B | 6–12 | 3.4 | [55] |
Co–B/MCM-41 | - | 3–30 | 2 | - |
Co–B/FSM-16 | - | 3–30 | 2.1 | - |
Co–B/non-porous | - | 30 | 0.9 | - |
unsupported Co–B | - | 30–40 | 0.6 | - |
Co–B/C-film | - | 50–300 | 0.6 | [62] |
unsupported Co–B film | - | ~250 | 0.1 | - |
Co–W–P–B/Ni foam | - | 200–400 | - | [64] |
Ru@ZK-4 | Ru | 2.9 | 90 | [66] |
Ni@3D-(N)GFs | Ni | 2–4 | 41.7 | [67] |
p(HEMA)-Co | Co | - | 3.8 | [81] |
p(HEMA)-Ni | Ni | - | 0.8 | - |
p(HEMA)-Cu | Cu | - | 1.1 | - |
p(SPM)-Co | Co | - | 5.8 | [82] |
p(SPM)-Ni | Ni | - | 3.8 | - |
p(SPM)-Cu | Cu | - | 1.8 | - |
p(VPA)-Co | Co | - | 7.7 | [85] |
p(VPA)-Ni | Ni | - | 3.6 | - |
p(VPA)-Cu | Cu | - | 1.1 | - |
Co-MOF | Co | <10 | 20.8 | [98] |
Ni-ZIF-8 | Ni | 2.7 | 14.2 | [99] |
Pt@MIL-101(Cr) | Pt | 1.2–3 | 446.4 | [46] |
AuNi@MIL-101(Cr) | AuNi | 2.9–3.4 | 66.2 | [103] |
AuCo@MIL101(Cr) | AuCo | 1.8 | 23.5 | [102] |
3. Nanostructured Materials
4. Conclusions
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Umegaki, T.; Xu, Q.; Kojima, Y. Porous Materials for Hydrolytic Dehydrogenation of Ammonia Borane. Materials 2015, 8, 4512-4534. https://doi.org/10.3390/ma8074512
Umegaki T, Xu Q, Kojima Y. Porous Materials for Hydrolytic Dehydrogenation of Ammonia Borane. Materials. 2015; 8(7):4512-4534. https://doi.org/10.3390/ma8074512
Chicago/Turabian StyleUmegaki, Tetsuo, Qiang Xu, and Yoshiyuki Kojima. 2015. "Porous Materials for Hydrolytic Dehydrogenation of Ammonia Borane" Materials 8, no. 7: 4512-4534. https://doi.org/10.3390/ma8074512